Mayr's Database of Reactivity Parameters

H-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles
1 | 2 | 3 | 4 « Back Found 193 molecules, displaying page 1 of 4 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
((dimethylsilyl)methyl)trimethylsilane
C6H18Si2*
 dichloromethane

N  Param.: 4.86

sN Param.: 0.64		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
((methylsilanediyl)bis(methylene))bis(trimethylsilane)
C9H26Si3*
 dichloromethane

N  Param.: 4.91

sN Param.: 0.64		**Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(2,2-diphenylethyl)diethyl(methyl)silane
*
 dichloromethane

N  Param.: -6.40

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(2-([1,1'-biphenyl]-4-yl)ethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: -0.80

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(3-chlorobenzyl)dimethylsilane
C9H13ClSi*
 dichloromethane

N  Param.: 1.30

sN Param.: 0.75		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4,4-dimethylpentyl)trimethylstannane
*
 dichloromethane/MeCN mix

N  Param.: -3.90

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-(tert-butyl)phenethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: -0.30

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-chlorophenethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: -1.80

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-chlorophenyl)dimethylsilane
C8H11ClSi*
 dichloromethane

N  Param.: 3.05

sN Param.: 0.73		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-methoxyphenethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: 0.20

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-methoxyphenyl)dimethylsilane
C9H14OSi*
 dichloromethane

N  Param.: 4.23

sN Param.: 0.73		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(chloromethyl)dimethylsilane
C3H9ClSi*
 dichloromethane

N  Param.: 0.80

sN Param.: 0.73		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(E,E)-2,5-heptadiene
C7H12*
 dichloromethane

N  Param.: -0.74

sN Param.: 0.99		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
C9H28Si4*
 dichloromethane

N  Param.: 3.61

sN Param.: 0.79		***Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1,1,3,3-pentamethyldisiloxane
C5H16OSi2*
 dichloromethane

N  Param.: 3.12

sN Param.: 0.73		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilepane
*
 dichloromethane

N  Param.: -3.10

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsiletane
*
 dichloromethane

N  Param.: -2.10

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilinane
C7H16Si*
 dichloromethane

N  Param.: -2.40

sN Param.: 1.10		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilolane
*
 dichloromethane

N  Param.: -3.86

sN Param.: 1.10		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,2,4,5-tetramethylcyclohexa-1,4-diene (in CH2Cl2)
C10H16*
 dichloromethane

N  Param.: 4.27

sN Param.: 0.86		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,2-dihydronaphthalene (in MeCN)
C10H10*
 MeCN

N  Param.: -3.30

sN Param.: 1.00		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3,5-trimethylcyclohexa-1,4-diene (in CH2Cl2)
C9H14*
 dichloromethane

N  Param.: 4.95

sN Param.: 0.79		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C26H37N2P*
 MeCN

N  Param.: 19.85

sN Param.: 0.34		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-bis(trimethylgermyl)propane (in MeCN)
*
 MeCN

N  Param.: -3.40

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-bis(trimethylsilyl)propane
*
 dichloromethane/MeCN mix

N  Param.: -5.30

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-bis(trimethylstannyl)propane (in MeCN)
*
 MeCN

N  Param.: -1.70

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-di-tert-butyl-1,3,2-diazaphosphinane (in MeCN)
C11H25N2P*
 MeCN

N  Param.: 13.46

sN Param.: 0.52		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphospholidine (in MeCN)
C10H23N2P*
 MeCN

N  Param.: 18.74

sN Param.: 0.47		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C10H21N2P*
 MeCN

N  Param.: 25.54

sN Param.: 0.35		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-2,3-dihydro-1H-benzo[d][1,3,2]diazaphosphole (in MeCN)
C14H23N2P*
 MeCN

N  Param.: 20.93

sN Param.: 0.43		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-dimesityl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C20H25N2P*
 MeCN

N  Param.: 17.68

sN Param.: 0.68		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-dioxepane
*
 dichloromethane

N  Param.: -3.80

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-dioxolane
C3H6O2*
 dichloromethane

N  Param.: -2.86

sN Param.: 0.80		***Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-cyclohexadiene
C6H8*
 dichloromethane

N  Param.: 0.09

sN Param.: 0.98		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-cyclohexadiene (in MeCN)
*
 MeCN

N  Param.: 0.35

sN Param.: 0.98		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dihydronaphthalene
C10H10*
 dichloromethane

N  Param.: -0.07

sN Param.: 1.03		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-dihydronaphthalene (in MeCN)
C10H10*
 MeCN

N  Param.: -2.50

sN Param.: 1.00		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dimethylcyclohexa-1,4-diene (in CH2Cl2)
C8H12*
 dichloromethane

N  Param.: 1.88

sN Param.: 0.96		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,4-pentadiene
C5H8*
 dichloromethane

N  Param.: -2.99

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,6-bis(trimethylsilyl)hexane
*
 dichloromethane

N  Param.: -4.70

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1-methylsiletane
C4H10Si*
 dichloromethane

N  Param.: 2.30

sN Param.: 0.75		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1-methylsilolane
C5H12Si*
 dichloromethane

N  Param.: 2.20

sN Param.: 0.75		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
10-methyl-9,10-dihydroacridine
*
 dichloromethane

N  Param.: 5.54

sN Param.: 0.90		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
10-methyl-9,10-dihydroacridine (in MeCN)
C14H13N*
 MeCN

N  Param.: 4.00

sN Param.: 0.70		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (anti)
*
 dichloromethane

N  Param.: -3.00

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.50

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-(3-chlorophenyl)-1,3-dimethyl-benzimidazoline (in MeCN)
*
 MeCN

N  Param.: 9.38

sN Param.: 0.71		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-(4-(trifluoromethyl)phenyl)-1,3-dimethyl-benzimidazoline (in MeCN)
*
 MeCN

N  Param.: 8.74

sN Param.: 0.71		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-(4-nitrophenyl)-1,3-dimethyl-benzimidazoline (in MeCN)
*
 MeCN

N  Param.: 8.36

sN Param.: 0.71		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-(p-anisyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.01

sN Param.: 0.72		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322