Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-(p-tolyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.14

sN Param.: 0.70		 *** Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
cycloheptatriene (in MeCN)
C7H8 *
 MeCN

N  Param.: 0.55

sN Param.: 0.97		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-cyclohexadiene (in MeCN)
*
 MeCN

N  Param.: 0.35

sN Param.: 0.98		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-dioxolane
C3H6O2 *
 dichloromethane

N  Param.: -2.86

sN Param.: 0.80		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-propyl-1,3-dioxolane
C6H12O2 *
 dichloromethane

N  Param.: -1.06

sN Param.: 0.81		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-phenyldioxolane
C9H10O2 *
 dichloromethane

N  Param.: -0.90

sN Param.: 0.80		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in MeCN)
*
 MeCN

N  Param.: 9.80

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 50W50AN)
*
 water-MeCN mix

N  Param.: 9.79

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 67W33AN)
*
 water-MeCN mix

N  Param.: 10.19

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 80W20AN)
*
 water-MeCN mix

N  Param.: 10.67

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839