Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-(4-nitrophenyl)-1,3-dimethyl-benzimidazoline (in MeCN)
*
 MeCN

N  Param.: 8.36

sN Param.: 0.71		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
isopropanol (in aq. sulfuric acid)
C3H8O *
 water

N  Param.: -2.60

sN Param.: 0.80		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetraethylsilane
*
 MeCN

N  Param.: -6.50

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
butyltrimethylsilane
*
 dichloromethane

N  Param.: -5.40

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(phenethyl)silane
*
 dichloromethane

N  Param.: -3.50

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(2,2-diphenylethyl)diethyl(methyl)silane
*
 dichloromethane

N  Param.: -6.40

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,6-bis(trimethylsilyl)hexane
*
 dichloromethane

N  Param.: -4.70

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-bis(trimethylsilyl)propane
*
 dichloromethane/MeCN mix

N  Param.: -5.30

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsiletane
*
 dichloromethane

N  Param.: -2.10

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilepane
*
 dichloromethane

N  Param.: -3.10

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839