Mayr's Database of Reactivity Parameters

N-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-phenyl-N-(phenylmethyl)methanimine (in CH2Cl2)
C14H13N *
 dichloromethane

N  Param.: 7.90

sN Param.: 0.76		 ** Z. Naturforsch. B 2013, 68b, 693-699
10.5560/ZNB.2013-3085
N-phenylpropan-2-imine (in CH2Cl2)
C9H11N *
 dichloromethane

N  Param.: 9.53

sN Param.: 0.85		 *** Z. Naturforsch. B 2013, 68b, 693-699
10.5560/ZNB.2013-3085
N-(phenylmethyl)propan-2-imine (in CH2Cl2)
C10H13N *
 dichloromethane

N  Param.: 11.13

sN Param.: 0.73		 *** Z. Naturforsch. B 2013, 68b, 693-699
10.5560/ZNB.2013-3085
N-phenylcyclohexanimine (in CH2Cl2)
C12H15N *
 dichloromethane

N  Param.: 8.80

sN Param.: 1.00		 *** Z. Naturforsch. B 2013, 68b, 693-699
10.5560/ZNB.2013-3085
1,1-dimethyl-2-methylenehydrazine (in CH2Cl2)
C3H8N2 *
 dichloromethane

N  Param.: 19.31

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2013, 52, 11900-11904
10.1002/anie.201305092
N-methylenepyrrolidin-1-amine (in CH2Cl2)
C5H10N2 *
 dichloromethane

N  Param.: 17.90

sN Param.: 0.48		 *** Angew. Chem. Int. Ed. 2013, 52, 11900-11904
10.1002/anie.201305092
4-(2-(fluorodiphenylmethyl)pyrrolidin-1-yl)pyridine
C22H21FN2 *
 dichloromethane

N  Param.: 14.57

sN Param.: 0.75		 *** Eur. J. Org. Chem. 2014, , 1202-1211
10.1002/ejoc.201301730
2-phenylethylamine (in water)
C8H11N *
 water

N  Param.: 13.40

sN Param.: 0.57		 *** ChemPlusChem 2015, 80, 1673-1679
10.1002/cplu.201500246
nicotine (in CH2Cl2)
C10H14N2 *
 dichloromethane

N  Param.: 10.40

sN Param.: 1.04		 *** J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
nicotine (in MeCN)
C10H14N2 *
 MeCN

N  Param.: 11.60

sN Param.: 0.81		 *** J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580