Mayr's Database of Reactivity Parameters

Aliphatic amines

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
triethylamine (in CH2Cl2)
*
 dichloromethane

N  Param.: 17.30

sN Param.: 0.52		*J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-pyrrolidine (in CH2Cl2)
*
 dichloromethane

N  Param.: 20.60

sN Param.: 0.52		*J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-piperidine (in CH2Cl2)
*
 dichloromethane

N  Param.: 18.90

sN Param.: 0.52		*J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-morpholine (in CH2Cl2)
*
 dichloromethane

N  Param.: 16.50

sN Param.: 0.52		*J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
1-methyl-2-phenylpyrrolidine (in CH2Cl2)
C11H15N*
 dichloromethane

N  Param.: 16.80

sN Param.: 0.49		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
2,2,2-trifluoroethylamine (in DMSO)
C2H4F3N*
 DMSO

N  Param.: 12.15

sN Param.: 0.65		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
ethyl glycinate (in DMSO)
C4H9NO2*
 DMSO

N  Param.: 14.30

sN Param.: 0.67		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
n-propylamine (in DMSO)
C3H9N*
 DMSO

N  Param.: 15.70

sN Param.: 0.64		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
morpholine (in DMSO)
C4H9NO*
 DMSO

N  Param.: 16.96

sN Param.: 0.67		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
piperidine (in DMSO)
C5H11N*
 DMSO

N  Param.: 17.19

sN Param.: 0.71		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y