Mayr's Database of Reactivity Parameters

Azoles and Azole Anions

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Azoles and Azole Anions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
imidazole (in 91M9AN)
C3H4N2 *
 MeOH-MeCN mix

N  Param.: 10.41

sN Param.: 0.70		 *** Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542
imidazole (in MeCN)
*
 MeCN

N  Param.: 11.47

sN Param.: 0.79		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
imidazole (in DMSO)
*
 DMSO

N  Param.: 11.58

sN Param.: 0.79		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
imidazole (in water)
*
 water

N  Param.: 9.63

sN Param.: 0.57		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
1-methyl-imidazole (in MeCN)
*
 MeCN

N  Param.: 11.90

sN Param.: 0.73		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
1-methyl-imidazole (in water)
*
 water

N  Param.: 9.91

sN Param.: 0.55		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
1-phenyl-imidazole (in MeCN)
*
 MeCN

N  Param.: 11.31

sN Param.: 0.67		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
2-methyl-imidazole (in MeCN)
*
 MeCN

N  Param.: 11.74

sN Param.: 0.76		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
2-methyl-imidazole (in water)
*
 water

N  Param.: 9.45

sN Param.: 0.54		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
4-methyl-imidazole (in MeCN)
*
 MeCN

N  Param.: 11.79

sN Param.: 0.77		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b