Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
91% methanol/9% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 7.45

sN Param.: 0.87		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% methanol/20% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 7.20

sN Param.: 0.89		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% methanol/33% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 7.01

sN Param.: 0.91		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% methanol/50% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 6.67

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% methanol/67% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 6.38

sN Param.: 0.92		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% methanol/80% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 6.04

sN Param.: 0.94		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% methanol/90% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 5.55

sN Param.: 0.97		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z