Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles
1 | 2 | 3 Forward » Found 57 molecules, displaying page 3 of 3 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
10% methanol/90% MeCN (v/v)
CH4O*
 MeOH-MeCN mix

N  Param.: 5.55

sN Param.: 0.97		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
91% n-propanol/9% MeCN (v/v)
C3H8O*
 nPrOH-MeCN mix

N  Param.: 7.05

sN Param.: 0.80		***Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
91% propan-2-ol/9% MeCN (v/v)
C3H8O*
 iPrOH-MeCN mix

N  Param.: 6.49

sN Param.: 0.96		***Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
DMSO (O attack)
*
 DMSO

N  Param.: 11.30

sN Param.: 0.74		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
50% water/50% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.50

sN Param.: 1.03		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
30% water/70% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.65

sN Param.: 0.96		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
10% water/90% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.96

sN Param.: 0.93		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
7% water/93% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.34

sN Param.: 0.96		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
5% water/95% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -0.10

sN Param.: 0.97		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
3% water/97% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.19

sN Param.: 1.08		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
2% water/98% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.62

sN Param.: 1.10		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
1% water/99% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.93

sN Param.: 1.09		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
methanol (in MeCN)
*
 MeCN

N  Param.: 6.86

sN Param.: 0.73		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
ethanol (in MeCN)
*
 MeCN

N  Param.: 7.13

sN Param.: 0.71		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
isopropanol (in MeCN)
*
 MeCN

N  Param.: 6.82

sN Param.: 0.70		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
tert-butanol (in MeCN)
*
 MeCN

N  Param.: 5.35

sN Param.: 0.72		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
water (in MeCN)
*
 MeCN

N  Param.: 5.79

sN Param.: 0.72		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360