S- and Se-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
3,5-bis(trifluoromethyl)thiophenolate (in DMSO)	DMSO	N Param.: 19.71 s_N Param.: 0.86	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-(trifluoromethyl)thiophenolate (in DMSO)	DMSO	N Param.: 21.30 s_N Param.: 0.86	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
3-(trifluoromethyl)thiophenolate (in DMSO)	DMSO	N Param.: 21.75 s_N Param.: 0.86	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
3-chlorothiophenolate (in DMSO)	DMSO	N Param.: 22.50 s_N Param.: 0.78	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-bromothiophenolate (in DMSO)	DMSO	N Param.: 22.80 s_N Param.: 0.78	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
thiophenolate (in DMSO)	DMSO	N Param.: 23.36 s_N Param.: 0.74	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-methylthiophenolate (in DMSO)	DMSO	N Param.: 24.35 s_N Param.: 0.69	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
naphthalene-2-thiolate (in DMSO)	DMSO	N Param.: 22.55 s_N Param.: 0.83	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-methoxythiophenolate (in DMSO)	DMSO	N Param.: 24.97 s_N Param.: 0.68	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
SO3(2-) (in water)	water	N Param.: 16.83 s_N Param.: 0.56	J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y