Mayr's Database of Reactivity Parameters

S-substituted carbocations

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Carbocations » S-substituted carbocations

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-phenyl-1,3-dithiolan-2-ylium ion
C9H9S2 *

E Param.: -5.91, Deviation: ±0.33

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-phenyl-1,3-dithianylium ion
C10H11S2 *

E Param.: -6.43, Deviation: ±0.04

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1,3-dithianylium ion
C4H7S2 *

E Param.: -2.14, Deviation: ±0.07

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c