Mayr's Database of Reactivity Parameters

Carboxylates and Carbonates

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles
« Back Forward » Found 11 molecules, displaying page 1 of 1 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
acetate (in MeCN)
*
 MeCN

N  Param.: 16.90

sN Param.: 0.75		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 90A10W)
*
 aq acetone

N  Param.: 12.71

sN Param.: 0.68		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 80A20W)
*
 aq acetone

N  Param.: 12.50

sN Param.: 0.60		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
benzoate (in MeCN)
*
 MeCN

N  Param.: 16.82

sN Param.: 0.70		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
benzoate (in 90AN10W)
*
 aq MeCN

N  Param.: 11.30

sN Param.: 0.72		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
p-nitrobenzoate (in MeCN)
*
 MeCN

N  Param.: 15.30

sN Param.: 0.76		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
p-nitrobenzoate (in acetone)
*
 acetone

N  Param.: 18.74

sN Param.: 0.68		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
3,5-dinitrobenzoate (in MeCN)
*
 MeCN

N  Param.: 14.90

sN Param.: 0.71		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
3,5-dinitrobenzoate (in acetone)
*
 acetone

N  Param.: 18.80

sN Param.: 0.62		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
benzoate (inMeCN)
*
 MeCN

N  Param.: 16.45

sN Param.: 0.72		***J. Am. Chem. Soc. 2020, 142, 5221-5233
10.1021/jacs.9b12998
methyl carbonate (in MeCN)
*
 MeCN

N  Param.: 16.03

sN Param.: 0.64		***Eur. J. Org. Chem. 2010, , 4205-4210
10.1002/ejoc.201000414