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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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57 | 58 | 59 | 60 | 61 | 62 | 63 | 64 | 65Found 1712 molecules, page 61 of 86
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-aminobutan-1-ol (in DMSO)
*
 DMSO

N  Param.: 14.39

sN Param.: 0.67		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
propargylamine (in water)
C3H5N*
 water

N  Param.: 12.29

sN Param.: 0.59		***J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
2-(triphenylsiloxy)propene
*
 dichloromethane

N  Param.: 4.46

sN Param.: 0.90		*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
anion of (benzylsulfonyl)benzene (in DMSO)
C13H11O2S*
 DMSO

N  Param.: 25.77

sN Param.: 0.56		***Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
1-methylsulfanylpropan-2-one (in DMSO)
C4H8OS*
 DMSO

E Param.: -15.60

*J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
hypochlorite (in water)
ClO*
 water

N  Param.: 14.50

sN Param.: 0.58		***Org. Lett. 2018, 20, 2816-2820
10.1021/acs.orglett.[...]
allylamine (in water)
C3H7N*
 water

N  Param.: 13.21

sN Param.: 0.54		***J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO)
C7H10ClO4*
 DMSO

N  Param.: 18.19

sN Param.: 0.74		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
trimethylamine (in MeCN)
*
 MeCN

N  Param.: 23.05

sN Param.: 0.45		***J. Org. Chem. 2012, 77, 8142-8155
10.1021/jo301497g
tetrapropylstannane (in 1,2-DCE)
*
 1,2-dichloroethane

N  Param.: -0.50

sN Param.: 1.13		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
n-butylamine (in MeCN)
*
 MeCN

N  Param.: 15.27

sN Param.: 0.63		***Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
bromo(phenylsulfonyl)methanide (in DMSO)
C7H6BrO2S*
 DMSO

N  Param.: 23.90

sN Param.: 0.62		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
[H-B(2,6-F2C6H3)3]- [NEt4]+
*
 MeCN

N  Param.: 13.97

sN Param.: 0.66		***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298
phenyl isothiocyanate
C7H5NS*
 DMSO

E Param.: -18.15

***J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960
3-methyl-2,4-dioxotetrahydro-2H-pyran-3-ide (in DMSO)
C6H7O3*
 DMSO

N  Param.: 14.46

sN Param.: 0.91		***Eur. J. Org. Chem. 2015, , 7594-7601
10.1002/ejoc.201501107
tris(4-methoxyphenyl)methane (in MeCN)
*
 MeCN

N  Param.: -5.18

sN Param.: 0.82		*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
anion of ethyl 2-cyano-2-phenylacetate (in DMSO)
C11H10NO2*
 DMSO

N  Param.: 15.85

sN Param.: 1.04		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
isopropylamine (in MeCN)
*
 MeCN

N  Param.: 13.77

sN Param.: 0.70		***Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
(4,4-dimethylpentyl)trimethylstannane
*
 dichloromethane/MeCN mix

N  Param.: -3.90

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-methyl-N-((trifluoromethyl)thio)-aniline
*

E Param.: -23.32

*Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859

News

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  • 02/23/26:
    Isochalcogenoureas (O, S, Se & Te derivatives) have been added (ChemistryEurope 2026, 4, e202500443 & Angew. Chem. Int. Ed. 2025, 64, e202514865).
  • 01/30/25:
    Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
  • 05/22/24:
    Lactone enolates have been added (JOC 2024, 89, 6915-6928).
  • 11/13/24:
    2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
  • 05/21/24:
    Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
  • 10/19/23:
    Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
  • 09/28/23:
    Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
  • 07/05/23:
    S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
  • 03/16/23:
    Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
  • 01/30/23:
    NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
  • 09/20/22:
    Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
  • 01/30/23:
    Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
  • 01/30/23:
    Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
  • 01/30/23:
    Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
  • 04/13/21:
    Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
  • 05/21/21:
    Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
  • 05/06/20:
    Heteroallenes added (JACS 2020, 142, 8383-8402).
  • 01/27/20:
    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
  • 01/30/23:
    Phenolates added (JOC 2019, 84, 8837-8858)
  • 04/24/18:
    Ketones added (JACS 2018, 140, 5500).
  • 11/03/17:
    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).