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Name	Solvent	Reactivity Parameters	Reference (title or year)
2,4-dimethyl-imidazole (in MeCN)	MeCN	N Param.: 11.51 s_N Param.: 0.84	Org. Biomol. Chem. 2010, 8, 1929-1935 10.1039/c000965b
2,4-dimethyl-imidazole anion (in DMSO)	DMSO	N Param.: 20.69 s_N Param.: 0.60	Chem. Eur. J. 2012, 18, 127-137 10.1002/chem.201102411
2,4-dimethyl-penta-1,4-diene	dichloromethane	N Param.: 0.54 s_N Param.: 1.00	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2,4-dimethylpyrrole	MeCN	N Param.: 10.67 s_N Param.: 0.91	Eur. J. Org. Chem. 2008, , 2369-2374 10.1002/ejoc.200800092
2,4-dinitrothiophene		E Param.: -12.33	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
2,5-dichloroquinone (C-Cl)		E Param.: -16.11	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
2,5-dichloroquinone (C-H)		E Param.: -12.28	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
2,5-dimethyl-benzimidazole (in DMSO)	DMSO	N Param.: 10.21 s_N Param.: 0.85	Org. Biomol. Chem. 2010, 8, 1929-1935 10.1039/c000965b
2,5-dimethyl-hexa-1,5-diene	dichloromethane	N Param.: 1.14 s_N Param.: 1.00	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2,5-dimethylindole	MeCN	N Param.: 7.22 s_N Param.: 1.10	J. Org. Chem. 2006, 71, 9088-9095 10.1021/jo0614339
2,5-dimethylpyrrole	MeCN	N Param.: 8.01 s_N Param.: 0.96	Eur. J. Org. Chem. 2008, , 2369-2374 10.1002/ejoc.200800092
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -11.68	Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295
2,6-di-tert-butyl-4-(methoxymethylene)cyclohexa-2,5-dien-1-one		E Param.: -15.10	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert-butyl-4-ethylidenecyclohexa-2,5-dien-1-one		E Param.: -13.68	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dien-1-one		E Param.: -11.17	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone		E Param.: -14.50	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone		E Param.: -15.03	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone		E Param.: -14.36	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone		E Param.: -17.18	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone		E Param.: -16.38	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299

News

01/30/26:
Isochalcogenoureas (O, S, Se & Te derivatives) have been added (Angew. Chem. Int. Ed. 2025, 64, e202514865).
01/30/25:
Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
05/22/24:
Lactone enolates have been added (JOC 2024, 89, 6915-6928).
11/13/24:
2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
05/21/24:
Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
10/19/23:
Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
09/28/23:
Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
07/05/23:
S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
03/16/23:
Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
01/30/23:
NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
09/20/22:
Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
01/30/23:
Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
01/30/23:
Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
01/30/23:
Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
04/13/21:
Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
05/21/21:
Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
05/06/20:
Heteroallenes added (JACS 2020, 142, 8383-8402).
01/27/20:
Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
05/06/20:
GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
01/30/23:
Phenolates added (JOC 2019, 84, 8837-8858)
04/24/18:
Ketones added (JACS 2018, 140, 5500).
11/03/17:
Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
04/23/18:
Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
04/23/18:
Michael acceptors added (JACS 2017, 139, 13318).
06/16/17:
Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).