Mayr's Database of Reactivity Parameters

transition metal hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » transition metal hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
HMo(Cp)(CO)3
*
 dichloromethane

N  Param.: 4.88

sN Param.: 0.80		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3(C5H4CO2Me)
*
 dichloromethane

N  Param.: -0.90

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HMn(CO)5
*
 dichloromethane

N  Param.: 1.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HCr(CO)3Cp*
*
 dichloromethane

N  Param.: 1.60

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3Cp
*
 dichloromethane

N  Param.: 1.70

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
cis-HMn(PCy3)(CO)4
*
 dichloromethane

N  Param.: 2.20

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
cis-HMn(PPh3)(CO)4
*
 dichloromethane

N  Param.: 2.30

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3(C5H4Me)
*
 dichloromethane

N  Param.: 2.40

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3Cp*
*
 dichloromethane

N  Param.: 3.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3(indenyl)
*
 dichloromethane

N  Param.: 3.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839