Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2)	dichloromethane	N Param.: 7.98 s_N Param.: 0.71	J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768
6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2)	dichloromethane	N Param.: 4.67 s_N Param.: 0.92	J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768
bis(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 15.68 s_N Param.: 0.74	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
fluorobis(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 17.46 s_N Param.: 0.73	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
methoxybis(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 17.29 s_N Param.: 0.70	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)	DMSO	N Param.: 16.06 s_N Param.: 0.69	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-fluoro-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)	DMSO	N Param.: 19.03 s_N Param.: 0.58	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)	DMSO	N Param.: 17.36 s_N Param.: 0.71	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)	DMSO	N Param.: 18.81 s_N Param.: 0.59	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)	DMSO	N Param.: 20.51 s_N Param.: 0.64	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616