Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
tris(2,4-dimethylphenyl)phosphane	dichloromethane	N Param.: 14.88 s_N Param.: 0.41	Chem. Eur. J. 2017, 23, 7422-7427 10.1002/chem.201701080
tris(2,6-dimethoxyphenyl)phosphane (in MeCN)	MeCN	N Param.: 18.11 s_N Param.: 0.62	Chem. Eur. J. 2017, 23, 7422-7427 10.1002/chem.201701080
tris(2-methoxyphenyl)phosphane	dichloromethane	N Param.: 14.26 s_N Param.: 0.73	Chem. Eur. J. 2017, 23, 7422-7427 10.1002/chem.201701080
tris(2-methylphenyl)phosphane	dichloromethane	N Param.: 8.56 s_N Param.: 0.70	Chem. Eur. J. 2017, 23, 7422-7427 10.1002/chem.201701080
t-butylperoxy anion (in H2O)	water	N Param.: 14.29 s_N Param.: 0.51	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
cumene peroxy anion (in H2O)	water	N Param.: 13.92 s_N Param.: 0.61	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
phthalimidoperoxyhexanoate (in H2O)	water	N Param.: 16.02 s_N Param.: 0.54	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
2-phenylperoxyacetate (in H2O)	water	N Param.: 15.63 s_N Param.: 0.56	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
3,5-dichloroperoxybenzoate (in H2O)	water	N Param.: 17.93 s_N Param.: 0.50	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
magnesium 2-carboperoxybenzoate (in H2O)	water	N Param.: 18.43 s_N Param.: 0.46	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
3-chloroperoxybenzoate (in H2O)	water	N Param.: 18.19 s_N Param.: 0.47	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
4-fluoroperoxybenzoate (in H2O)	water	N Param.: 17.99 s_N Param.: 0.47	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
4-nitroperoxybenzoate (in H2O)	water	N Param.: 17.43 s_N Param.: 0.50	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
4-methoxyperoxybenzoate (in H2O)	water	N Param.: 17.84 s_N Param.: 0.46	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
3-chloro-4-methoxyperoxybenzoate (in H2O)	water	N Param.: 18.56 s_N Param.: 0.48	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
peroxybenzoate (in H2O)	water	N Param.: 18.57 s_N Param.: 0.43	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
barbiturate anion (in DMSO)	DMSO	N Param.: 15.59 s_N Param.: 0.80	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223
1,3-dimethylbarbiturate anion (in DMSO)	DMSO	N Param.: 17.46 s_N Param.: 0.72	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223
2-thiobarbiturate anion (in DMSO)	DMSO	N Param.: 14.24 s_N Param.: 0.82	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223
1,3-diethyl-thiobarbiturate anion (in DMSO)	DMSO	N Param.: 14.90 s_N Param.: 0.80	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223