Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
pyrrolidine (in 91M9AN)	MeOH-MeCN mix	N Param.: 15.97 s_N Param.: 0.63	Angew. Chem. Int. Ed. 2006, 45, 3869-3874 10.1002/anie.200600542
pyrrolidine (in water)	water	N Param.: 17.21 s_N Param.: 0.49	J. Org. Chem. 2007, 72, 3679-3688 10.1021/jo062586z
pyrrolidine (inMeCN)	MeCN	N Param.: 18.58 s_N Param.: 0.61	J. Am. Chem. Soc. 2020, 142, 1526-1547 10.1021/jacs.9b11877
quinidine	dichloromethane	N Param.: 10.54 s_N Param.: 0.74	J. Org. Chem. 2009, 74, 7157-7164 10.1021/jo901670w
quinine	dichloromethane	N Param.: 10.46 s_N Param.: 0.75	J. Org. Chem. 2009, 74, 7157-7164 10.1021/jo901670w
quinuclidine (in MeCN)	MeCN	N Param.: 20.54 s_N Param.: 0.60	Angew. Chem. Int. Ed. 2007, 46, 6176-6179 10.1002/anie.200701489
saccharin anion (in MeCN)	MeCN	N Param.: 10.78 s_N Param.: 0.89	J. Org. Chem. 2010, 75, 5250-5258 10.1021/jo1009883
Se-BTM (in CH2Cl2)	dichloromethane	N Param.: 14.27 s_N Param.: 0.63	Angew. Chem. Int. Ed. 2025, EarlyView, e202514865 10.1002/anie.202514865
Se-DHPB (in CH2Cl2)	dichloromethane	N Param.: 15.16 s_N Param.: 0.66	Angew. Chem. Int. Ed. 2025, EarlyView, e202514865 10.1002/anie.202514865
Se-HBTM (in CH2Cl2)	dichloromethane	N Param.: 14.42 s_N Param.: 0.67	Angew. Chem. Int. Ed. 2025, EarlyView, e202514865 10.1002/anie.202514865