Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles
22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 Found 588 molecules, displaying page 28 of 30 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
3-mesityl-1-methyl-1H-imidazol-3-ium-2-ide (in THF)
C13H16N2*
 THF

N  Param.: 21.50

sN Param.: 0.45		***Org. Lett. 2016, 18, 3566-3569
10.1021/acs.orglett.[...]
anion of nitroethane (in DMSO)
C2H4NO2*
 DMSO

N  Param.: 21.54

sN Param.: 0.62		***J. Org. Chem. 2003, 68, 6880-6886
10.1021/jo0344182
1-(4-(dimethylamino)pyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO)
C15H17N2O*
 DMSO

N  Param.: 21.61

sN Param.: 0.58		***J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
1,3-dimesityl-1H-imidazol-3-ium-2-ide (in THF)
C21H24N2*
 THF

N  Param.: 21.72

sN Param.: 0.45		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
anion of nitroethane (in DMF)
C2H4NO2- *
 DMF

N  Param.: 22.21

sN Param.: 0.48		***Chem. Eur. J. 2008, 14, 6108-6118
10.1002/chem.200800329
1,3-Bis(2,6-diisopropylphenyl)-4-methylene-5-(4-(trifluoromethyl)phenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)
C34H40F3N3*
 THF

N  Param.: 22.30

sN Param.: 0.49		***Angew. Chem. Int. Ed. 2023, 62, e202309790
10.1002/anie.202309790
anion of (4-CN-C6H4)CH2SO2Ph (in DMSO)
C14H10NO2S-*
 DMSO

N  Param.: 22.60

sN Param.: 0.57		***Org. Biomol. Chem. 2008, 6, 3052-3058
10.1039/b805604h
1,3-bis(2,6-diisopropylphenyl)-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)
C33H41N3*
 THF

N  Param.: 22.80

sN Param.: 0.60		***Angew. Chem. Int. Ed. 2023, 62, e202309790
10.1002/anie.202309790
anion of diethyl 2-butylmalonate (in DMSO)
C11H19O4*
 DMSO

N  Param.: 23.00

sN Param.: 0.55		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
3-(2,6-dimethoxyphenyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF)
C12H14N2O2*
 THF

N  Param.: 23.00

sN Param.: 0.46		***Org. Lett. 2016, 18, 3566-3569
10.1021/acs.orglett.[...]
anion of 1,2-diphenylethanone (in DMSO)
C14H11O*
 DMSO

N  Param.: 23.15

sN Param.: 0.60		***Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
2-(pyrid-4-yl)CH(-)CO2Et (in DMSO)
C9H10NO2*
 DMSO

N  Param.: 23.27

sN Param.: 0.70		***Eur. J. Org. Chem. 2013, , 4255-4261
10.1002/ejoc.201300265
1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium-2-ide (in THF)
C21H26N2*
 THF

N  Param.: 23.35

sN Param.: 0.40		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
1,3-Bis(2,6-diisopropylphenyl)-5-(4-methoxyphenyl)-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)
C34H43N3O*
 THF

N  Param.: 23.55

sN Param.: 0.56		***Angew. Chem. Int. Ed. 2023, 62, e202309790
10.1002/anie.202309790
2-(4-CN-C6H4)CH(-)CO2Et (in DMSO)
C11H10NO2*
 DMSO

N  Param.: 23.64

sN Param.: 0.65		***Eur. J. Org. Chem. 2013, , 4255-4261
10.1002/ejoc.201300265
lithium indenide (in DMSO)
C9H7Li*
 DMSO

N  Param.: 23.66

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
sodium indenide (in DMSO)
C9H7Na*
 DMSO

N  Param.: 23.74

sN Param.: 0.71		***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
bromo(phenylsulfonyl)methanide (in DMSO)
C7H6BrO2S*
 DMSO

N  Param.: 23.90

sN Param.: 0.62		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
potassium indenide (in DMSO)
C9H7K*
 DMSO

N  Param.: 24.16

sN Param.: 0.68		***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
anion of (4-CF3-C6H4)CH2SO2Ph (in DMSO)
C14H10F3O2S-*
 DMSO

N  Param.: 24.30

sN Param.: 0.51		***Org. Biomol. Chem. 2008, 6, 3052-3058
10.1039/b805604h