C-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
anion of ethyl cyanoacetate (in DMSO)	DMSO	N Param.: 19.62 s_N Param.: 0.67	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
anion of diethyl malonate (in DMSO)	DMSO	N Param.: 20.22 s_N Param.: 0.65	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
cyanide (in MeCN)	MeCN	N Param.: 16.27 s_N Param.: 0.70	Angew. Chem. Int. Ed. 2005, 44, 142-145 10.1002/anie.200461640
tert-butyl isocyanide	dichloromethane	N Param.: 5.47 s_N Param.: 0.77	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
benzyl isocyanide	dichloromethane	N Param.: 4.90 s_N Param.: 0.74	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
2,6-dimethylphenyl isocyanide	dichloromethane	N Param.: 4.59 s_N Param.: 0.87	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
p-tosylmethyl isocyanide (TosMIC)	dichloromethane	N Param.: 3.50 s_N Param.: 0.76	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
4-cyanophenyl isocyanide	dichloromethane	N Param.: 3.57 s_N Param.: 0.72	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
(4-Br-C6H4)-(CO)-CH=SMe2	dichloromethane	N Param.: 11.95 s_N Param.: 0.76	Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933
(cyclohexen-1-yl)prolinate (in MeCN)	MeCN	N Param.: 18.86 s_N Param.: 0.70	Angew. Chem. Int. Ed. 2010, 49, 9526-9529 10.1002/anie.201004344