C-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 19.49 s_N Param.: 0.63	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
2-oxo-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO)	DMSO	N Param.: 19.46 s_N Param.: 0.58	J. Am. Chem. Soc. 2013, 135, 15216-15224 10.1021/ja407885h
1-methyl-2-methylene-3-phenyl-1,2-dihydropyridine (in DMSO)	DMSO	N Param.: 19.41 s_N Param.: 0.61	Eur. J. Org. Chem. 2024, , accepted 10.1002/ejoc.202400373
2-oxo-2-phenyl-1-(quinolin-1-ium-1-yl)ethan-1-ide (in DMSO)	DMSO	N Param.: 19.38 s_N Param.: 0.50	J. Am. Chem. Soc. 2013, 135, 15216-15224 10.1021/ja407885h
anion of malononitrile (in DMSO)	DMSO	N Param.: 19.36 s_N Param.: 0.67	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
1-(4-(tert-butyl)phenyl)-2-methylene-4,6-diphenyl-1,2-dihydropyridine (in DMSO)	DMSO	N Param.: 19.36 s_N Param.: 0.68	Eur. J. Org. Chem. 2024, , accepted 10.1002/ejoc.202400373
anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 19.35 s_N Param.: 0.67	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of N,N-diethyl-3-oxo-3-phenylpropanoate (in DMSO)	DMSO	N Param.: 19.28 s_N Param.: 0.65	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500
(EtO)2P(O)CH(-)CO2Et (in DMSO)	DMSO	N Param.: 19.23 s_N Param.: 0.65	J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216
anion of diethyl 2-cyclohexylmalonate (in DMSO)	DMSO	N Param.: 19.23 s_N Param.: 0.67	Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107