C-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
Me2S=CH(4-CN-C6H4) (in DMSO)	DMSO	N Param.: 21.07 s_N Param.: 0.68	J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF)	THF	N Param.: 20.78 s_N Param.: 0.61	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 20.72 s_N Param.: 0.58	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of nitromethane (in DMSO)	DMSO	N Param.: 20.71 s_N Param.: 0.60	J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j
1,3-diethoxy-2-fluoro-1,3-dioxopropan-2-ide (in DMSO)	DMSO	N Param.: 20.63 s_N Param.: 0.76	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
anion of 2-nitropropane (in DMSO)	DMSO	N Param.: 20.61 s_N Param.: 0.69	J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j
MeSO-CH-CO2Et (in DMSO)	DMSO	N Param.: 20.61 s_N Param.: 0.64	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
1-(ethoxycarbonyl)-2-oxocyclododecan-1-ide (in DMSO)	DMSO	N Param.: 20.60 s_N Param.: 0.63	Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)	DMSO	N Param.: 20.51 s_N Param.: 0.64	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
3-(4-methoxyphenyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF)	THF	N Param.: 20.41 s_N Param.: 0.46	Org. Lett. 2016, 18, 3566-3569 10.1021/acs.orglett.[...]