Mayr's Database of Reactivity Parameters

C-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate
C18H21BF3LiO2S*
MeCN

N  Param.: 6.24

sN Param.: 1.00
**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
potassium trifluoro(furan-2-yl)borate
C4H3BF3KO*
MeCN

N  Param.: 5.99

sN Param.: 0.79
**J. Am. Chem. Soc. 2013, 135, 6317-6324
10.1021/ja4017655
(1H-inden-1-yl)trimethylsilane (in CH2Cl2)
C12H16Si*
dichloromethane

N  Param.: -0.10

sN Param.: 1.05
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
(1H-inden-1-yl)trimethylstannane (in CH2Cl2)
C12H16Sn*
dichloromethane

N  Param.: 6.68

sN Param.: 0.81
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
(1H-inden-1-yl)zinc(II) bromide*LiBr (in DMSO)
C9H7Br2LiZn*
DMSO

N  Param.: 15.60

sN Param.: 0.51
**Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
(1H-inden-1-yl)zinc(II) chloride*LiCl (in DMSO)
C9H7Cl2LiZn*
DMSO

N  Param.: 18.10

sN Param.: 0.46
**Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
(1S)-(-)-alpha-pinene
C10H16*
dichloromethane

N  Param.: 0.68

sN Param.: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2,3-dimethylbut-2-enyl)triethylsilane
C12H26Si*
dichloromethane

N  Param.: 3.15

sN Param.: 1.15
*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2-methylallyl)benzene
C10H12*
dichloromethane

N  Param.: 0.25

sN Param.: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2-methylallyl)dicarbonyl(cyclopentadienyl)iron(II)
*
dichloromethane

N  Param.: 8.45

sN Param.: 0.83
***Helv. Chim. Acta 2005, 88, 1754-1768
10.1002/hlca.200590137