Mayr's Database of Reactivity Parameters

Metallocenes

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(Cp*)2Zr(Me)2 - Dimethyl-bis(pentamethylcyclopentadienyl)zirconium
C22H36Zr*
 dichloromethane

N  Param.: 5.49

sN Param.: 1.06		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Ti(CH2Ph)2 - Dibenzyltitanocene
*
 dichloromethane

N  Param.: 4.38

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Zr(CH2Ph)2 - Dibenzylzirconocene
*
 dichloromethane

N  Param.: 5.10

sN Param.: 1.03		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Zr(Me)2 - Dimethylzirconocene
*
 dichloromethane

N  Param.: 4.35

sN Param.: 1.09		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Dimethyl 1,1'-isopropylidenezirconocene
*
 dichloromethane

N  Param.: 5.20

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Dimethyl bis(indenyl)zirconium(IV)
*
 dichloromethane

N  Param.: 6.89

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452