Mayr's Database of Reactivity Parameters

Isothioureas

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Isochalkogenoureas
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(R)-2-(tert-butyl)-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine
*
 dichloromethane

N  Param.: 12.95

sN Param.: 0.58		***J. Org. Chem. 2011, 76, 5104-5112
10.1021/jo200803x
(S)-3,3-difluoro-2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine (in CH2Cl2)
C16H12F2N2S*
 dichloromethane

N  Param.: 10.83

sN Param.: 0.80		***ARKIVOC 2024, (4), 202312093
10.24820/ark.5550190[...]
ITU1
*
 dichloromethane

N  Param.: 13.86

sN Param.: 0.68		***Angew. Chem. Int. Ed. 2025, , in print
10.1002/anie.202514865
ITU2
*
 dichloromethane

N  Param.: 13.06

sN Param.: 0.73		***Angew. Chem. Int. Ed. 2025, , in print
10.1002/anie.202514865