Electrophiles
Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
---|---|---|---|---|
oxan-4-one (in DMSO) | DMSO | E Param.: -17.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 | |
thian-4-one (in DMSO) | DMSO | E Param.: -16.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 | |
1,4-dioxaspiro[4.5]decan-8-one (in DMSO) | DMSO | E Param.: -18.20 | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 | |
pentan-2-one (in DMSO) | DMSO | E Param.: -22.30 | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 | |
1-methylsulfanylpropan-2-one (in DMSO) | DMSO | E Param.: -15.60 | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 | |
N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide | E Param.: -6.06 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate | E Param.: -10.46 | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | ||
N-fluoro-2,6-dichloropyridinium tetrafluoroborate | E Param.: -5.29 | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | ||
Selectfluor | E Param.: -5.20 | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | ||
NFSI | MeCN | E Param.: -8.44 | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
N-fluoropyridinium tetrafluoroborate | E Param.: -9.89 | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | ||
N-(trifluoromethyl)thio)phthalimide | E Param.: -11.92 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
N-(trifluoromethyl)thio)saccharin | E Param.: -6.48 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
N-(trifluoromethyl)thio)succinimide | E Param.: -12.56 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
N-(difluoromethyl)thio)phthalimide | E Param.: -11.86 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide | E Param.: -13.44 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
N-methyl-N-((trifluoromethyl)thio)-aniline | E Param.: -23.32 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane | E Param.: -13.77 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane | E Param.: -14.52 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | ||
3-methylcyclopentenone | DMSO | E Param.: -28.90 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
2-methylcyclopentenone | DMSO | E Param.: -22.10 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
cyclopentenone | DMSO | E Param.: -20.60 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
furan-2(5H)-one | DMSO | E Param.: -20.70 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
2-methylcyclohexenone | DMSO | E Param.: -27.50 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
cyclohexenone | DMSO | E Param.: -22.10 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
dihydro-2H-pyran-2-one | DMSO | E Param.: -21.80 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
3-methylenetetrahydropyran-2-one | DMSO | E Param.: -19.50 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
3-methylenedihydrofuranone | DMSO | E Param.: -19.40 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -17.00 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -16.84 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -16.25 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -17.42 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -11.68 | Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295 | |
ethyl 3-nitro-1H-indole-1-carboxylate | E Param.: -14.10 | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | ||
3-nitro-1-tosyl-1H-indole | E Param.: -14.87 | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | ||
4-bromo-3-nitro-1-tosyl-1H-indole | E Param.: -14.60 | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | ||
phenyl isocyanate | MeCN | E Param.: -15.38 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
p-tosyl isocyanate | MeCN | E Param.: -7.69 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
phenyl isothiocyanate | DMSO | E Param.: -18.15 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
p-nitrophenyl isothiocyanate | DMSO | E Param.: -15.89 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
diphenylcarbodiimide | DMSO | E Param.: -20.14 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
carbon disulfide | DMSO | E Param.: -17.70 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
3-methylcyclohexenone | DMSO | E Param.: -29.60 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
3,6-dinitro-1-tosyl-1H-indole | E Param.: -12.90 | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | ||
4-phenylbut-3-yn-2-one | E Param.: -16.90 | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | ||
hex-3-yn-2-one | E Param.: -17.90 | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | ||
cycloheptenone | DMSO | E Param.: -22.00 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
methyl diazoacetate | E Param.: -18.50 | Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376 | ||
dimethyl diazomalonate | E Param.: -18.20 | Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376 | ||
(p-nitrophenyl)diazomethane | E Param.: -18.30 | Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376 |