Carbanions

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)	DMSO	N Param.: 18.81 s_N Param.: 0.59	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)	DMSO	N Param.: 20.51 s_N Param.: 0.64	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-ethoxy-1-methoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)	DMSO	N Param.: 19.15 s_N Param.: 0.59	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
1,3-diethoxy-2-fluoro-1,3-dioxopropan-2-ide (in DMSO)	DMSO	N Param.: 20.63 s_N Param.: 0.76	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO)	DMSO	N Param.: 18.19 s_N Param.: 0.74	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
1,2,3-trimethoxy-1,3-dioxopropan-2-ide (in DMSO)	DMSO	N Param.: 20.08 s_N Param.: 0.74	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
chloro(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 28.27 s_N Param.: 0.42	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844
bromo(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 23.90 s_N Param.: 0.62	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844
chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO)	DMSO	N Param.: 25.59 s_N Param.: 0.51	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844
chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO)	DMSO	N Param.: 24.88 s_N Param.: 0.49	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844