Carbanions

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Name	Solvent	Reactivity Parameters	Reference (title or year)
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN)	MeCN	N Param.: 16.15 s_N Param.: 0.99	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 17.33 s_N Param.: 0.74	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 20.72 s_N Param.: 0.58	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 3-oxo-3-phenylpropanenitrile (in DMSO)	DMSO	N Param.: 16.55 s_N Param.: 0.78	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500
anion of 3-methyl acetylacetone (in water)	water	N Param.: 14.33 s_N Param.: 0.69	J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e
anion of 3-methyl acetylacetone (in DMSO)	DMSO	N Param.: 18.38 s_N Param.: 0.72	J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e
anion of 2-phenylmalononitrile (in DMSO)	DMSO	N Param.: 15.58 s_N Param.: 1.00	Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513
anion of 2-phenyl-propionitrile (in DMSO)	DMSO	N Param.: 28.95 s_N Param.: 0.58	J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x
anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO)	DMSO	N Param.: 15.97 s_N Param.: 0.72	Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513
anion of 2-nitropropane (in water)	water	N Param.: 10.69 s_N Param.: 0.56	J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j