Mayr's Database of Reactivity Parameters

Carbanions in DMSO

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of 2-nitro-1-phenylethan-1-one (in DMSO)
C8H6NO3*
 DMSO

N  Param.: 13.91

sN Param.: 0.76		***Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of diethyl 2-(acetyl)malonate (in DMSO)
C9H13O5*
 DMSO

N  Param.: 13.83

sN Param.: 0.84		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
5-(4-cyanobenzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C14H12NO4*
 DMSO

N  Param.: 13.79

sN Param.: 0.86		***Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
anion of diethyl 2-(benzoyl)malonate (in DMSO)
C14H15O5*
 DMSO

N  Param.: 13.63

sN Param.: 0.80		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of 5-(p-anisyl) Meldrum's acid (in DMSO)
C13H13O5*
 DMSO

N  Param.: 12.35

sN Param.: 0.90		**Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
2,2-dimethyl-5-(4-nitrobenzyl)-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C13H12NO6*
 DMSO

N  Param.: 12.02

sN Param.: 1.17		***Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
anion of 5-phenyl Meldrum's acid (in DMSO)
C12H11O4*
 DMSO

N  Param.: 11.54

sN Param.: 0.95		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107