Mayr's Database of Reactivity Parameters

Carbanions in DMSO

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO)
C19H20NO2-*
 DMSO

N  Param.: 27.77

sN Param.: 0.47		***Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]
chloro(phenylsulfonyl)methanide (in DMSO)
C7H6ClO2S*
 DMSO

N  Param.: 28.27

sN Param.: 0.42		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
anion of 2-phenyl-propionitrile (in DMSO)
C9H8N-*
 DMSO

N  Param.: 28.95

sN Param.: 0.58		***J. Org. Chem. 2009, 74, 75-81
10.1021/jo802241x
1-((4-chlorobenzylidene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)
*
 DMSO

N  Param.: 29.02

sN Param.: 0.49		**Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]
1-(benzylideneamino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)
*
 DMSO

N  Param.: 29.10

sN Param.: 0.50		*Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]
cyano((diphenylmethylene)amino)methanide
*
 DMSO

N  Param.: 29.50

sN Param.: 0.50		*Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]
2-(benzylideneamino)-1-ethoxy-1-oxopropan-2-ide (in DMSO)
*
 DMSO

N  Param.: 30.82

sN Param.: 0.41		**Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]