Carbanions in DMSO

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-thiobarbiturate anion (in DMSO)	DMSO	N Param.: 14.24 s_N Param.: 0.82	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223
1,3-diethyl-thiobarbiturate anion (in DMSO)	DMSO	N Param.: 14.90 s_N Param.: 0.80	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223
1-((diphenylmethylene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)	DMSO	N Param.: 26.95 s_N Param.: 0.52	Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...]
2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO)	DMSO	N Param.: 27.77 s_N Param.: 0.47	Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...]
1-ethoxy-3-(4-nitrophenyl)-1,3-dioxopropan-2-ide (in DMSO)	DMSO	N Param.: 16.26 s_N Param.: 0.83	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
enolate of 3-isochromanone (in DMSO)	DMSO	N Param.: 25.39 s_N Param.: 0.54	J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277
enolate of 2-coumaranone (in DMSO)	DMSO	N Param.: 19.60 s_N Param.: 0.75	J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277