Mayr's Database of Reactivity Parameters

Carbanions in DMSO

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions
1 | 2 | 3 | 4 | 5 | 6 Found 117 molecules, displaying page 2 of 6 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-(4-NO2-C6H4)CH(-)CO2Et (in DMSO)
C10H10NO4*
 DMSO

N  Param.: 20.00

sN Param.: 0.71		***Eur. J. Org. Chem. 2013, , 4255-4261
10.1002/ejoc.201300265
2-(benzylideneamino)-1-ethoxy-1-oxopropan-2-ide (in DMSO)
*
 DMSO

N  Param.: 30.82

sN Param.: 0.41		**Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]
2-(pyrid-4-yl)CH(-)CO2Et (in DMSO)
C9H10NO2*
 DMSO

N  Param.: 23.27

sN Param.: 0.70		***Eur. J. Org. Chem. 2013, , 4255-4261
10.1002/ejoc.201300265
2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO)
C19H20NO2-*
 DMSO

N  Param.: 27.77

sN Param.: 0.47		***Tetrahedron 2019, 75, 459-463
10.1016/j.tet.2018.1[...]
2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO)
C7H10ClO4*
 DMSO

N  Param.: 18.19

sN Param.: 0.74		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
C10H10FO4S*
 DMSO

N  Param.: 20.51

sN Param.: 0.64		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-ethoxy-1-methoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
C11H13O5S*
 DMSO

N  Param.: 19.15

sN Param.: 0.59		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
C10H11O4S*
 DMSO

N  Param.: 18.81

sN Param.: 0.59		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-fluoro-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
C7H4FO4S2*
 DMSO

N  Param.: 19.03

sN Param.: 0.58		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
C8H7O5S2*
 DMSO

N  Param.: 17.36

sN Param.: 0.71		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-PhCH(-)CO2Et (in DMSO)
C10H11O2*
 DMSO

N  Param.: 27.54

sN Param.: 0.57		***Eur. J. Org. Chem. 2013, , 4255-4261
10.1002/ejoc.201300265
2-thiobarbiturate anion (in DMSO)
C4H3N2O2S*
 DMSO

N  Param.: 14.24

sN Param.: 0.82		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
C7H5O4S2*
 DMSO

N  Param.: 16.06

sN Param.: 0.69		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
3-acetyl-2-oxotetrahydro-2H-pyran-3-ide (in DMSO)
C7H9O3*
 DMSO

N  Param.: 17.00

sN Param.: 0.74		***Eur. J. Org. Chem. 2015, , 7594-7601
10.1002/ejoc.201501107
3-methyl-2,4-dioxotetrahydro-2H-pyran-3-ide (in DMSO)
C6H7O3*
 DMSO

N  Param.: 14.46

sN Param.: 0.91		***Eur. J. Org. Chem. 2015, , 7594-7601
10.1002/ejoc.201501107
5-(4-(dimethylamino)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C15H18NO4*
 DMSO

N  Param.: 14.48

sN Param.: 0.86		***Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
5-(4-(methoxy)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C14H15O5*
 DMSO

N  Param.: 15.13

sN Param.: 0.75		***Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
5-(4-cyanobenzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C14H12NO4*
 DMSO

N  Param.: 13.79

sN Param.: 0.86		***Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
5-benzyl-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C13H13O4*
 DMSO

N  Param.: 15.02

sN Param.: 0.75		***Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
anion of (3-nitrophenyl)nitromethane (in DMSO)
C7H5N2O4-*
 DMSO

N  Param.: 18.06

sN Param.: 0.71		***J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j