Carbanions in DMSO

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Name	Solvent	Reactivity Parameters	Reference (title or year)
anion of 4-(trifluoromethyl)benzyl-CN (in DMSO)	DMSO	N Param.: 27.28 s_N Param.: 0.50	J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x
1-((diphenylmethylene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)	DMSO	N Param.: 26.95 s_N Param.: 0.52	Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...]
chloro((4-chlorophenyl)sulfonyl)methanide (in DMSO)	DMSO	N Param.: 26.90 s_N Param.: 0.45	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844
anion of (benzylsulfonyl)benzene (in DMSO)	DMSO	N Param.: 25.77 s_N Param.: 0.56	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500
chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO)	DMSO	N Param.: 25.59 s_N Param.: 0.51	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844
anion of 2-(4-CN-C6H4)propionitrile (in DMSO)	DMSO	N Param.: 25.35 s_N Param.: 0.56	J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x
anion of 4-cyanobenzyl-CN (in DMSO)	DMSO	N Param.: 25.11 s_N Param.: 0.54	J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x
anion of 1-phenylpropan-2-one (in DMSO)	DMSO	N Param.: 24.99 s_N Param.: 0.60	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500
chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO)	DMSO	N Param.: 24.88 s_N Param.: 0.49	J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844
anion of (4-CF3-C6H4)CH2SO2Ph (in DMSO)	DMSO	N Param.: 24.30 s_N Param.: 0.51	Org. Biomol. Chem. 2008, 6, 3052-3058 10.1039/b805604h