Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
diethylmercury (in MeCN)
*
 MeCN

N  Param.: -0.70

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4,4-dimethylpentyl)trimethylstannane
*
 dichloromethane/MeCN mix

N  Param.: -3.90

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylstannyl)propyl)silane (in MeCN)
*
 MeCN

N  Param.: -3.40

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-bis(trimethylstannyl)propane (in MeCN)
*
 MeCN

N  Param.: -1.70

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylgermyl)propyl)silane (in MeCN)
*
 MeCN

N  Param.: -4.80

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylstannyl)propyl)germane (in MeCN)
*
 MeCN

N  Param.: -2.40

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-bis(trimethylgermyl)propane (in MeCN)
*
 MeCN

N  Param.: -3.40

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylplumbyl)propyl)silane (in MeCN)
*
 MeCN

N  Param.: -1.20

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylplumbyl)propyl)germane (in MeCN)
*
 MeCN

N  Param.: -1.00

sN Param.: 1.10		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
diethylether (in dichloromethane)
*
 dichloromethane

N  Param.: -5.10

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrahydrofuran (in dichloromethane)
C4H8O*
 dichloromethane

N  Param.: -3.50

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethoxymethane
*
 dichloromethane

N  Param.: -4.90

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-methyl-1,3-dioxolane
*
 dichloromethane

N  Param.: -3.30

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
4,5-dimethyl-1,3-dioxolane (anti)
*
 dichloromethane

N  Param.: -2.40

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (anti)
*
 dichloromethane

N  Param.: -3.00

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-ethyl-4,5-dimethyl-1,3-dioxolane (anti)
*
 dichloromethane

N  Param.: -2.90

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
4,5-dimethyl-2-vinyl-1,3-dioxolane
*
 dichloromethane

N  Param.: -2.60

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-isopropyl-4,5-dimethyl-1,3-dioxolane (ani)
*
 dichloromethane

N  Param.: -4.10

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.50

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-ethyl-4,5-dimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.40

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-isopropyl-4,5-dimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -3.50

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-dioxepane
*
 dichloromethane

N  Param.: -3.80

sN Param.: 0.80		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tri-p-tolylmethane (in MeCN)
C22H22*
 MeCN

N  Param.: -8.80

sN Param.: 0.82		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
bis(4-methoxyphenyl)phenylmethane (in MeCN)
C21H20O2*
 MeCN

N  Param.: -7.00

sN Param.: 0.82		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tris(4-(dimethylamino)phenyl)methane (in MeCN)
C25H31N3*
 MeCN

N  Param.: -3.30

sN Param.: 0.82		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
bis(4-(dimethylamino)phenyl)phenylmethane (in MeCN)
C23H26N2*
 MeCN

N  Param.: -4.20

sN Param.: 0.82		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
10-methyl-9,10-dihydroacridine (in MeCN)
C14H13N*
 MeCN

N  Param.: 4.00

sN Param.: 0.70		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dihydronaphthalene (in MeCN)
C10H10*
 MeCN

N  Param.: -2.50

sN Param.: 1.00		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,2-dihydronaphthalene (in MeCN)
C10H10*
 MeCN

N  Param.: -3.30

sN Param.: 1.00		-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
Hantzsch ester
C13H19NO4*
 dichloromethane

N  Param.: 9.00

sN Param.: 0.90		***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-benzyl-1,4-dihydronicotineamide
C13H14N2O*
 dichloromethane

N  Param.: 8.67

sN Param.: 0.82		***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-benzyl-1,4-dihydronicotineamide (in 90W10AN)
C13H14N2O*
 water-MeCN mix

N  Param.: 11.35

sN Param.: 0.66		***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-phenyl-1,4-dihydronicotineamide
C12H12N2O*
 dichloromethane

N  Param.: 7.53

sN Param.: 0.87		***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-(p-tolyl)-1,4-dihydronicotineamide
C13H14N2O*
 dichloromethane

N  Param.: 7.68

sN Param.: 0.95		***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-(p-anisyl)-1,4-dihydronicotineamide
C13H14N2O2*
 dichloromethane

N  Param.: 8.11

sN Param.: 0.92		***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
2-phenyl-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 9.72

sN Param.: 0.72		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-(p-anisyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.01

sN Param.: 0.72		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-(p-tolyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.14

sN Param.: 0.70		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
cycloheptatriene
C7H8*
 dichloromethane

N  Param.: 0.52

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-cyclohexadiene
C6H8*
 dichloromethane

N  Param.: 0.09

sN Param.: 0.98		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-dihydronaphthalene
C10H10*
 dichloromethane

N  Param.: -0.07

sN Param.: 1.03		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
9,10-dihydroanthracene
C14H12*
 dichloromethane

N  Param.: -0.86

sN Param.: 0.92		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
(E,E)-2,5-heptadiene
C7H12*
 dichloromethane

N  Param.: -0.74

sN Param.: 0.99		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
3-propylcyclopentene
C8H14*
 dichloromethane

N  Param.: -0.88

sN Param.: 0.94		***J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
xanthene
C13H10O*
 dichloromethane

N  Param.: 0.64

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
4-methyl-2,5-heptadiene
C8H14*
 dichloromethane

N  Param.: -0.73

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
3-methyl-1,4-pentadiene
C6H10*
 dichloromethane

N  Param.: -3.08

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-pentadiene
C5H8*
 dichloromethane

N  Param.: -2.99

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
p-cymene
C10H14*
 dichloromethane

N  Param.: -2.80

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
allylbenzene
C9H10*
 dichloromethane

N  Param.: -4.12

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538