Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
33% water/67% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.02

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.02

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% water/90% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 4.56

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
trifluoroethanol
C2H3F3O *
 TFE

N  Param.: 1.11

sN Param.: 0.96		 *** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
10% water/90%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 2.93

sN Param.: 0.88		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 3.20

sN Param.: 0.88		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
40% water/60%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 3.42

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% water/50%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 3.57

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
60% water/40%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 3.77

sN Param.: 0.88		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 4.78

sN Param.: 0.83		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z