Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
methanol (in MeCN)
*
 MeCN

N  Param.: 6.86

sN Param.: 0.73		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
ethanol (in MeCN)
*
 MeCN

N  Param.: 7.13

sN Param.: 0.71		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
isopropanol (in MeCN)
*
 MeCN

N  Param.: 6.82

sN Param.: 0.70		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
tert-butanol (in MeCN)
*
 MeCN

N  Param.: 5.35

sN Param.: 0.72		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
water (in MeCN)
*
 MeCN

N  Param.: 5.79

sN Param.: 0.72		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
10% water/90% acetone (v/v)
H2O*
 water-acetone mix

N  Param.: 5.70

sN Param.: 0.85		***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
20% water/80% acetone (v/v)
H2O*
 water-acetone mix

N  Param.: 5.77

sN Param.: 0.87		***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468