N-substituted carbocations (iminium ions)

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Name	Solvent	Reactivity Parameters	Reference (title or year)
p-AniCH=N+Me2 (in MeCN)	MeCN	E Param.: -10.69	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
PhCH=N+(CH2)4 (in MeCN)	MeCN	E Param.: -9.35	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
PhCH=N+(CH2)5 (in MeCN)	MeCN	E Param.: -9.60	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
p-CF3-C6H4-CH=N+Me2 (in MeCN)	MeCN	E Param.: -8.34	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium	dichloromethane	E Param.: -6.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864
(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium	dichloromethane	E Param.: -7.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864
MacMillan-iminium ion (1st generation)	MeCN	E Param.: -7.37	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
MacMillan-iminium ion (2nd generation)	MeCN	E Param.: -5.52	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
MacMillan-iminium ion (spiro)	MeCN	E Param.: -7.67	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
indolecarboxylate derived iminium ion	dichloromethane	E Param.: -9.50	Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933