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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
20% water/80% acetone (v/v)
H2O*
 water-acetone mix

N  Param.: 5.77

sN Param.: 0.87		***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
91% water/9% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 5.16

sN Param.: 0.91		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 5.04

sN Param.: 0.89		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% water/33% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 5.05

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% water/67% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 5.02

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 5.02

sN Param.: 0.89		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% water/90% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 4.56

sN Param.: 0.94		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
trifluoroethanol
C2H3F3O*
 TFE

N  Param.: 1.11

sN Param.: 0.96		***J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
10% water/90%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 2.93

sN Param.: 0.88		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 3.20

sN Param.: 0.88		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
40% water/60%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 3.42

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% water/50%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 3.57

sN Param.: 0.89		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
60% water/40%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 3.77

sN Param.: 0.88		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 4.78

sN Param.: 0.83		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
90% water/10%TFE (v/v)
H2O*
 water-TFE mix

N  Param.: 5.04

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
methanol
CH4O*
 MeOH

N  Param.: 7.54

sN Param.: 0.92		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
ethanol
C2H6O*
 EtOH

N  Param.: 7.44

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% water/90%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 7.03

sN Param.: 0.86		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.68

sN Param.: 0.85		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
40% water/60%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.28

sN Param.: 0.87		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z

News

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  • 01/30/23:
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  • 05/06/20:
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    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
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    Ketones added (JACS 2018, 140, 5500).
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    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).