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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | 22Found 1683 molecules, page 18 of 85
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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
furan-2(5H)-one
C4H4O2*
DMSO

E Param.: -20.70

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cyclopentanone (in DMSO)
C5H8O*
DMSO

E Param.: -21.00

*J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
diethyl 4-methyl-benzylidene malonate
C15H18O4*

E Param.: -21.11

***Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
diphenyldiazomethane
C13H10N2*

E Param.: -21.40

-Chem. Eur. J. 2022, 28, e202201376
10.1002/chem.202201376
diethyl 4-methoxy-benzylidene malonate
C15H18O5*

E Param.: -21.47

***Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
dihydro-2H-pyran-2-one
C5H6O2*
DMSO

E Param.: -21.80

**Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cycloheptenone
C7H10O*
DMSO

E Param.: -22.00

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cycloheptanone (in DMSO)
C7H12O*
DMSO

E Param.: -22.10

*J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
2-methylcyclopentenone
C6H8O*
DMSO

E Param.: -22.10

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cyclohexenone
C6H8O*
DMSO

E Param.: -22.10

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
pentan-2-one (in DMSO)
C5H10O*
DMSO

E Param.: -22.30

*J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
ethyl 2-methylprop-2-enoate (in DMSO)
C6H10O2*
DMSO

E Param.: -22.77

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
(E)-4-phenylbut-3-en-2-one (in DMSO)
C10H10O*
DMSO

E Param.: -23.01

***J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
diethyl 4-(dimethylamino)benzylidene malonate
C16H21NO4*

E Param.: -23.10

***Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
N-methyl-N-((trifluoromethyl)thio)-aniline
*

E Param.: -23.32

*Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate
C18H23NO4*

E Param.: -23.40

*Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
N,N-dimethylprop-2-enamide (in DMSO)
C5H9NO*
DMSO

E Param.: -23.54

***J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
ethyl (E)-but-2-enoate (in DMSO)
C6H10O2*
DMSO

E Param.: -23.59

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
diethyl 2-((julolidine-9-yl)methylene)malonate
C20H25NO4*

E Param.: -23.80

*Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
ethyl cinnamate (in DMSO)
C11H12O2*
DMSO

E Param.: -24.52

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106

News

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  • 01/30/25:
    Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
  • 05/22/24:
    Lactone enolates have been added (JOC 2024, 89, 6915-6928).
  • 11/13/24:
    2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
  • 05/21/24:
    Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
  • 10/19/23:
    Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
  • 09/28/23:
    Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
  • 07/05/23:
    S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
  • 03/16/23:
    Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
  • 01/30/23:
    NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
  • 09/20/22:
    Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
  • 01/30/23:
    Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
  • 01/30/23:
    Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
  • 01/30/23:
    Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
  • 04/13/21:
    Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
  • 05/21/21:
    Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
  • 05/06/20:
    Heteroallenes added (JACS 2020, 142, 8383-8402).
  • 01/27/20:
    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
  • 01/30/23:
    Phenolates added (JOC 2019, 84, 8837-8858)
  • 04/24/18:
    Ketones added (JACS 2018, 140, 5500).
  • 11/03/17:
    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).