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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-(triisopropylsiloxy)propene	dichloromethane	N Param.: 5.38 s_N Param.: 0.85	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
triphenylgermane	dichloromethane	N Param.: 3.99 s_N Param.: 0.62	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
triphenylstannane	dichloromethane	N Param.: 5.64 s_N Param.: 0.59	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
tributylgermane	dichloromethane	N Param.: 5.92 s_N Param.: 0.73	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
borane-triethylamine-complex	dichloromethane	N Param.: 8.90 s_N Param.: 0.75	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
tributylstannane	dichloromethane	N Param.: 9.96 s_N Param.: 0.55	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
2-(bis(trimethylsiloxy)amino)propene	dichloromethane	N Param.: 4.76 s_N Param.: 0.86	J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927
(bis(trimethylsiloxy)amino)styrene	dichloromethane	N Param.: 4.80 s_N Param.: 0.86	J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927
2-(bis(tert-butyldimethylsiloxy)amino)propene	dichloromethane	N Param.: 4.23 s_N Param.: 0.93	J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927
4-(bis(trimethylsiloxy)amino)pent-4-enoic acid methyl ester	dichloromethane	N Param.: 3.84 s_N Param.: 0.87	J. Org. Chem. 2001, 66, 3196-3200 10.1021/jo0015927
1-methylcyclohexene	dichloromethane	N Param.: 0.08 s_N Param.: 1.15	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
2-methyl-but-2-ene	dichloromethane	N Param.: 0.65 s_N Param.: 1.17	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
2-methylpropene (isobutylene)	dichloromethane	N Param.: 1.11 s_N Param.: 0.98	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
1-methyl-4-vinyl-benzene	dichloromethane	N Param.: 1.70 s_N Param.: 1.06	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
2-methyl-buta-1,3-diene (isoprene)	dichloromethane	N Param.: 1.10 s_N Param.: 0.98	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
trimethyl(prenyl)silane	dichloromethane	N Param.: 0.90 s_N Param.: 1.17	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
(2-methylallyl)triphenylgermane	dichloromethane	N Param.: 4.67 s_N Param.: 0.81	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
1-ethinylcyclohexenyl-Co2(CO)6	dichloromethane	N Param.: -0.44 s_N Param.: 1.06	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6	dichloromethane	N Param.: -1.11 s_N Param.: 0.92	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
cyclohepta-1,3,5-trienyl-Fe(CO)3	dichloromethane	N Param.: 3.42 s_N Param.: 0.94	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y

News

01/30/25:
Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
05/22/24:
Lactone enolates have been added (JOC 2024, 89, 6915-6928).
11/13/24:
2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
05/21/24:
Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
10/19/23:
Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
09/28/23:
Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
07/05/23:
S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
03/16/23:
Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
01/30/23:
NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
09/20/22:
Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
01/30/23:
Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
01/30/23:
Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
01/30/23:
Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
04/13/21:
Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
05/21/21:
Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
05/06/20:
Heteroallenes added (JACS 2020, 142, 8383-8402).
01/27/20:
Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
05/06/20:
GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
01/30/23:
Phenolates added (JOC 2019, 84, 8837-8858)
04/24/18:
Ketones added (JACS 2018, 140, 5500).
11/03/17:
Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
04/23/18:
Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
04/23/18:
Michael acceptors added (JACS 2017, 139, 13318).
06/16/17:
Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).