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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1% water/99% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.93

sN Param.: 1.09		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
10% water/90%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 7.03

sN Param.: 0.86		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.68

sN Param.: 0.85		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
40% water/60%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.28

sN Param.: 0.87		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% water/50%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.96

sN Param.: 0.89		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
60% water/40%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.81

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.54

sN Param.: 0.94		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
90% water/10%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.38

sN Param.: 0.91		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
chloride (in 80% aq EtOH)
Cl*
 water-EtOH mix

N  Param.: 13.00

sN Param.: 0.60		*J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
chloride (in 50% aq EtOH)
Cl*
 water-EtOH mix

N  Param.: 11.80

sN Param.: 0.60		*J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
bromide (in 80% aq EtOH)
Br*
 water-EtOH mix

N  Param.: 14.50

sN Param.: 0.60		*J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
bromide (in 50% aq EtOH)
Br*
 water-EtOH mix

N  Param.: 13.60

sN Param.: 0.60		*J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
fluoride (in 80% aq EtOH)
F*
 water-EtOH mix

N  Param.: 13.20

sN Param.: 0.53		*J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
10% water/90% acetone (v/v)
H2O*
 water-acetone mix

N  Param.: 5.70

sN Param.: 0.85		***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
20% water/80% acetone (v/v)
H2O*
 water-acetone mix

N  Param.: 5.77

sN Param.: 0.87		***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
H2O (in water)
H2O*
 water

N  Param.: 5.20

sN Param.: 0.89		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
OH- (in water)
HO*
 water

N  Param.: 10.47

sN Param.: 0.61		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
semicarbazide (in water)
CH5N3O*
 water

N  Param.: 11.05

sN Param.: 0.52		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
hydroxylamine (in water)
H3NO*
 water

N  Param.: 11.41

sN Param.: 0.55		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
2,2,2-trifluoroethanolate (in water)
C2H2F3O*
 water

N  Param.: 12.66

sN Param.: 0.59		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y

News

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  • 01/30/25:
    Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
  • 05/22/24:
    Lactone enolates have been added (JOC 2024, 89, 6915-6928).
  • 11/13/24:
    2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
  • 05/21/24:
    Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
  • 10/19/23:
    Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
  • 09/28/23:
    Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
  • 07/05/23:
    S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
  • 03/16/23:
    Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
  • 01/30/23:
    NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
  • 09/20/22:
    Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
  • 01/30/23:
    Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
  • 01/30/23:
    Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
  • 01/30/23:
    Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
  • 04/13/21:
    Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
  • 05/21/21:
    Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
  • 05/06/20:
    Heteroallenes added (JACS 2020, 142, 8383-8402).
  • 01/27/20:
    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
  • 01/30/23:
    Phenolates added (JOC 2019, 84, 8837-8858)
  • 04/24/18:
    Ketones added (JACS 2018, 140, 5500).
  • 11/03/17:
    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).