Mayr's Database of Reactivity Parameters

N-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,3-dimethylimidazolidin-2-imine
C5H11N3 *
 dichloromethane

N  Param.: 12.46

sN Param.: 0.87		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
N-(1,3-dimethylimidazolidin-2-ylidene)-1-phenylmethanamine
C12H17N3 *
 dichloromethane

N  Param.: 14.00

sN Param.: 0.70		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
2,3,5,6-tetrahydro-1H-imidazo[1,2-a]imidazole (TBO)
C5H9N3 *
 dichloromethane

N  Param.: 14.44

sN Param.: 0.79		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyrimidine (TBN)
C6H11N3 *
 dichloromethane

N  Param.: 16.15

sN Param.: 0.73		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
1-methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine (MeTBD)
C8H15N3 *
 dichloromethane

N  Param.: 14.43

sN Param.: 0.81		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine
C7H13N3 *
 dichloromethane

N  Param.: 16.16

sN Param.: 0.75		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
DBN (in CH2Cl2)
*
 dichloromethane

N  Param.: 15.50

sN Param.: 0.76		 *** ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
4-(dimethylamino)pyridine (in THF)
*
 THF

N  Param.: 15.90

sN Param.: 0.66		 *** Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
DBU (in THF)
*
 THF

N  Param.: 16.12

sN Param.: 0.67		 *** Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
acetonitrile (in MeCN)
*
 MeCN

N  Param.: 2.23

sN Param.: 0.84		 *** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b