Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
(S)-1-(3,5-bis(trifluoromethyl)phenyl)-3-(pyrrolidin-2-ylmethyl)thiourea	MeCN	N Param.: 14.97 s_N Param.: 0.69	J. Am. Chem. Soc. 2020, 142, 1526-1547 10.1021/jacs.9b11877
(R)-2-isopropylpyrrolidine	MeCN	N Param.: 16.44 s_N Param.: 0.71	J. Am. Chem. Soc. 2020, 142, 1526-1547 10.1021/jacs.9b11877
(R)-2-isopropyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine	dichloromethane	N Param.: 16.50 s_N Param.: 0.48	J. Org. Chem. 2011, 76, 5104-5112 10.1021/jo200803x
(R)-2-benzhydryl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine	dichloromethane	N Param.: 15.30 s_N Param.: 0.55	J. Org. Chem. 2011, 76, 5104-5112 10.1021/jo200803x
(R)-2-(tert-butyl)-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine	dichloromethane	N Param.: 12.95 s_N Param.: 0.58	J. Org. Chem. 2011, 76, 5104-5112 10.1021/jo200803x
(p-nitrophenyl)diazomethane	dichloromethane	N Param.: 7.17 s_N Param.: 0.83	J. Am. Chem. Soc. 2018, 140, 16758-16772 10.1021/jacs.8b09995
(p-cyanophenyl)diazomethane	dichloromethane	N Param.: 7.66 s_N Param.: 0.80	J. Am. Chem. Soc. 2018, 140, 16758-16772 10.1021/jacs.8b09995
(p-bromophenyl)diazomethane	dichloromethane	N Param.: 8.87 s_N Param.: 0.82	J. Am. Chem. Soc. 2018, 140, 16758-16772 10.1021/jacs.8b09995
(F)2-HBTM (in CH2Cl2)	dichloromethane	N Param.: 10.83 s_N Param.: 0.80	ARKIVOC 2024, (4), 202312093 10.24820/ark.5550190[...]
(EtO)2P(O)CH(-)CO2Et (in DMSO)	DMSO	N Param.: 19.23 s_N Param.: 0.65	J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216