Mayr's Database of Reactivity Parameters

Nucleophiles

19 | 20 | 21 | 22 | 23 | 24 | 25 | 26 | 27 Found 1310 molecules, displaying page 26 of 27 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
3-methylpyridine (in CH2Cl2)
C6H7N*
 dichloromethane

N  Param.: 10.90

sN Param.: 0.93		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
1-methyl-2-phenylpyrrolidine (in CH2Cl2)
C11H15N*
 dichloromethane

N  Param.: 16.80

sN Param.: 0.49		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
4-(morpholino)pyridine (in CH2Cl2)
C9H12N2O*
 dichloromethane

N  Param.: 14.59

sN Param.: 0.69		***Eur. J. Org. Chem. 2016, , 4050-4058
10.1002/ejoc.201600572
Cp2Zr(Me)2 - Dimethylzirconocene
*
 dichloromethane

N  Param.: 4.35

sN Param.: 1.09		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Zr(CH2Ph)2 - Dibenzylzirconocene
*
 dichloromethane

N  Param.: 5.10

sN Param.: 1.03		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Ti(CH2Ph)2 - Dibenzyltitanocene
*
 dichloromethane

N  Param.: 4.38

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
(Cp*)2Zr(Me)2 - Dimethyl-bis(pentamethylcyclopentadienyl)zirconium
C22H36Zr*
 dichloromethane

N  Param.: 5.49

sN Param.: 1.06		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Dimethyl 1,1'-isopropylidenezirconocene
*
 dichloromethane

N  Param.: 5.20

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Dimethyl bis(indenyl)zirconium(IV)
*
 dichloromethane

N  Param.: 6.89

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Meldrum's acid iodonium ylide (in CH2Cl2)
*
 dichloromethane

N  Param.: 4.36

sN Param.: 1.06		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
Dimedone iodonium ylide (in CH2Cl2)
*
 dichloromethane

N  Param.: 6.18

sN Param.: 0.81		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2)
*
 dichloromethane

N  Param.: 7.98

sN Param.: 0.71		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2)
*
 dichloromethane

N  Param.: 4.67

sN Param.: 0.92		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
ditert-butyl-phenylphosphane
C14H23P*
 dichloromethane

N  Param.: 12.40

sN Param.: 0.55		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2,6-dimethoxyphenyl)phosphane
C24H27O6P*
 dichloromethane

N  Param.: 15.19

sN Param.: 0.88		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2,4-dimethylphenyl)phosphane
C24H27P*
 dichloromethane

N  Param.: 14.88

sN Param.: 0.41		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2-methoxyphenyl)phosphane
C21H21O3P*
 dichloromethane

N  Param.: 14.26

sN Param.: 0.73		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2-methylphenyl)phosphane
C21H21P*
 dichloromethane

N  Param.: 8.56

sN Param.: 0.70		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
C9H17BO2*
 dichloromethane

N  Param.: -0.64

sN Param.: 1.10		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
(p-nitrophenyl)diazomethane
*
 dichloromethane

N  Param.: 7.17

sN Param.: 0.83		***J. Am. Chem. Soc. 2018, 140, 16758-16772
10.1021/jacs.8b09995
(p-cyanophenyl)diazomethane
*
 dichloromethane

N  Param.: 7.66

sN Param.: 0.80		***J. Am. Chem. Soc. 2018, 140, 16758-16772
10.1021/jacs.8b09995
(p-bromophenyl)diazomethane
*
 dichloromethane

N  Param.: 8.87

sN Param.: 0.82		***J. Am. Chem. Soc. 2018, 140, 16758-16772
10.1021/jacs.8b09995
dimethylsulfide (in CH2Cl2)
C2H6S*
 dichloromethane

N  Param.: 12.32

sN Param.: 0.72		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dimethylselenide (in CH2Cl2)
C2H6Se*
 dichloromethane

N  Param.: 12.60

sN Param.: 0.72		-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dibutylsulfide (in CH2Cl2)
C8H18S*
 dichloromethane

N  Param.: 11.86

sN Param.: 0.74		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiophene (in CH2Cl2)
C4H8S*
 dichloromethane

N  Param.: 13.10

sN Param.: 0.72		-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiopyran (in CH2Cl2)
C5H10S*
 dichloromethane

N  Param.: 11.94

sN Param.: 0.75		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
3-diazoindolin-2-one
C8H5N3O*
 dichloromethane

N  Param.: 3.16

sN Param.: 1.03		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazoindan-1-one
C9H6N2O*
 dichloromethane

N  Param.: 5.61

sN Param.: 0.65		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazocyclohexanone
C6H8N2O*
 dichloromethane

N  Param.: 3.44

sN Param.: 0.83		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazo-1-tetralone
C10H8N2O*
 dichloromethane

N  Param.: 3.51

sN Param.: 0.86		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazoindandione
C9H4N2O2*
 dichloromethane

N  Param.: 0.16

sN Param.: 0.86		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazo-1-benzosuberone
C11H10N2O*
 dichloromethane

N  Param.: 2.72

sN Param.: 0.96		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazobenzothiophen-3(2H)-one
C8H4N2OS*
 dichloromethane

N  Param.: 0.40

sN Param.: 0.93		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-((2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in CH2Cl2)
C17H21N3S*
 dichloromethane

N  Param.: 7.06

sN Param.: 1.11		***Chem. Commun. 2023, 59, 8091-8084
10.1039/d3cc01912h
diazocyclopentadiene (in CH2Cl2)
C5H4N2*
 dichloromethane

N  Param.: 4.84

sN Param.: 1.06		***Synthesis 2023, 55, 354-358
10.1055/s-0041-1737327
(E)-4-(ethylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in CH2Cl2)
C17H24N2S *
 dichloromethane

N  Param.: 8.13

sN Param.: 0.97		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(E)-4-(benzylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in CH2Cl2)
C22H26N2S *
 dichloromethane

N  Param.: 7.99

sN Param.: 0.98		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(S)-3,3-difluoro-2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine (in CH2Cl2)
C16H12F2N2S*
 dichloromethane

N  Param.: 10.83

sN Param.: 0.80		***ARKIVOC 2024, (4), 202312093
10.24820/ark.5550190[...]
2-methylpyridine (in CH2Cl2)
C6H7N*
 dichloromethane

N  Param.: 10.52

sN Param.: 0.78		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,6-dimethylpyridine (in CH2Cl2)
C7H9N*
 dichloromethane

N  Param.: 9.87

sN Param.: 0.68		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,4,6-trimethylpyridine (in CH2Cl2)
C8H11N*
 dichloromethane

N  Param.: 9.34

sN Param.: 0.71		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
methyl diazoacetate
C3H4N2O2*
 dichloromethane

N  Param.: 4.68

sN Param.: 0.94		***J. Am. Chem. Soc. 2023, 145, 7416-7434
10.1021/jacs.2c13872
dimethyl diazomalonate
C5H6N2O4*
 dichloromethane

N  Param.: -1.24

sN Param.: 0.81		***J. Am. Chem. Soc. 2023, 145, 7416-7434
10.1021/jacs.2c13872
pyridin-4-yl((trifluoromethyl)sulfonyl)amide (Ph4P+) (in CH2Cl2)
C6H4F3N2O2S-*
 dichloromethane

N  Param.: 17.88

sN Param.: 0.73		***J. Am. Chem. Soc. 2025, 147, 5043-5050
10.1021/jacs.4c14825
((4-methoxyphenyl)sulfonyl)(pyridin-4-yl)amide (Ph4P+) (in CH2Cl2)
C12H11N2O3S-*
 dichloromethane

N  Param.: 19.63

sN Param.: 0.65		***J. Am. Chem. Soc. 2025, 147, 5043-5050
10.1021/jacs.4c14825
benzoate (in 90AN10W)
*
 aq MeCN

N  Param.: 11.30

sN Param.: 0.72		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 90A10W)
*
 aq acetone

N  Param.: 12.71

sN Param.: 0.68		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 80A20W)
*
 aq acetone

N  Param.: 12.50

sN Param.: 0.60		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
p-nitrobenzoate (in acetone)
*
 acetone

N  Param.: 18.74

sN Param.: 0.68		***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464