Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-methylenetetrahydro-2H-pyran	dichloromethane	N Param.: 4.01 s_N Param.: 0.91	Angew. Chem. Int. Ed. 2026, 65, e24329 10.1002/anie.202524329
3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-5-methylenetetrahydrofuran	dichloromethane	N Param.: 5.50 s_N Param.: 0.76	Angew. Chem. Int. Ed. 2026, 65, e24329 10.1002/anie.202524329
4-((benzyloxy)methyl)-2,2-dimethyl-6-methylenetetrahydrofuro[3,4-d][1,3]dioxole	dichloromethane	N Param.: 5.35 s_N Param.: 0.88	Angew. Chem. Int. Ed. 2026, 65, e24329 10.1002/anie.202524329
8-(benzyloxy)-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxine	dichloromethane	N Param.: 1.94 s_N Param.: 1.24	Angew. Chem. Int. Ed. 2026, 65, e24329 10.1002/anie.202524329
3,4-bis(benzyloxy)-2-methyl-3,4-dihydro-2H-pyran	dichloromethane	N Param.: 2.04 s_N Param.: 1.20	Angew. Chem. Int. Ed. 2026, 65, e24329 10.1002/anie.202524329
phosphaethynolate ion (in MeCN)	MeCN	N Param.: 19.02 s_N Param.: 0.82	Chem. Sci. 2024, 15, 14406-14414 10.1039/D4SC03518F
8-MeO-HyperBTM	dichloromethane	N Param.: 15.70 s_N Param.: 0.63	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
7-MeO-HyperBTM (in CH2Cl2)	dichloromethane	N Param.: 14.95 s_N Param.: 2.67	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
7-MeS-HyperBTM (in CH2Cl2)	dichloromethane	N Param.: 14.62 s_N Param.: 0.67	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
7,8,9-(MeO)3-HyperBTM	dichloromethane	N Param.: 14.62 s_N Param.: 0.67	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
9-MeS-HyperBTM	dichloromethane	N Param.: 13.49 s_N Param.: 0.78	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
9-Me-HyperBTM	dichloromethane	N Param.: 14.76 s_N Param.: 0.67	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
7-PivO-HyperBTM	dichloromethane	N Param.: 14.49 s_N Param.: 0.66	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
7-Ms-HyperBTM	dichloromethane	N Param.: 12.52 s_N Param.: 0.75	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
HyperNTM	dichloromethane	N Param.: 14.47 s_N Param.: 0.72	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
HyperPTM	dichloromethane	N Param.: 13.43 s_N Param.: 0.79	ChemistryEurope 2026, 4, e202500434 10.1002/ceur.202500434
2-(1-azidovinyl)naphthalene (in Cyrene)	Cyrene (TM)	N Param.: 6.00 s_N Param.: 0.90	Chem. Commun. 2026, 62, 5041-5045 10.1039/d6cc00190d