Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.80	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
N-(difluoromethyl)thio)phthalimide		E Param.: -11.86	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone		E Param.: -11.87	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetonitrile		E Param.: -11.88	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
jul(S)BBS		E Param.: -11.89	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
N-(trifluoromethyl)thio)phthalimide		E Param.: -11.92	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
ethyl 2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetate		E Param.: -12.01	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
o-chloranil (C-Cl)		E Param.: -12.02	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -12.02	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
ethenesulfonyl fluoride (ESF)	DMSO	E Param.: -12.09	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
p-chloranil (C=O)		E Param.: -12.13	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
ani(Ph)2QM		E Param.: -12.18	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
di-tert-butyl azodicarboxylate	MeCN	E Param.: -12.23	Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598
2,5-dichloroquinone (C-H)		E Param.: -12.28	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
2,4-dinitrothiophene		E Param.: -12.33	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-nitro-<i>trans-beta</i>-nitrostyrene		E Param.: -12.37	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
N-(trifluoromethyl)thio)succinimide		E Param.: -12.56	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
4-cyano-<i>trans-beta</i>-nitrostyrene		E Param.: -12.61	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
dmaBBS		E Param.: -12.76	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
p-(dimethylamino)benzylidene Meldrum's acid		E Param.: -12.76	J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s