Mayr's Database of Reactivity Parameters

Alkenes

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Alkenes

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(E)-propenylbenzene
C9H10 *
 dichloromethane

N  Param.: -0.49

sN Param.: 1.18		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
styrene
C8H8 *
 dichloromethane

N  Param.: 0.78

sN Param.: 0.95		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
methylenecyclopentane
C6H10 *
 dichloromethane

N  Param.: 2.82

sN Param.: 0.90		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(Z)-but-2-ene
C4H8 *
 dichloromethane

N  Param.: -2.44

sN Param.: 1.09		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
methylenecyclopropane
C4H6 *
 dichloromethane

N  Param.: -0.47

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclobutane
C5H8 *
 dichloromethane

N  Param.: 1.65

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclohexane
C7H12 *
 dichloromethane

N  Param.: 1.16

sN Param.: 1.04		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
methylenecycloheptane
C8H14 *
 dichloromethane

N  Param.: 2.24

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclooctane
C9H16 *
 dichloromethane

N  Param.: 3.16

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclononane
C10H18 *
 dichloromethane

N  Param.: 2.57

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclodecane
C11H20 *
 dichloromethane

N  Param.: 2.82

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecycloundecane
C12H22 *
 dichloromethane

N  Param.: 2.33

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclododecane
C13H24 *
 dichloromethane

N  Param.: 1.52

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclopentadecane
C16H30 *
 dichloromethane

N  Param.: 1.69

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
propene
C3H6 *
 dichloromethane

N  Param.: -2.41

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-chloropropene
C3H5Cl *
 dichloromethane

N  Param.: -3.65

sN Param.: 1.97		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1-hexene
C6H12 *
 dichloromethane

N  Param.: -2.77

sN Param.: 1.41		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1-methylcyclohexene
C7H12 *
 dichloromethane

N  Param.: 0.08

sN Param.: 1.15		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methyl-but-2-ene
C5H10 *
 dichloromethane

N  Param.: 0.65

sN Param.: 1.17		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methylpropene (isobutylene)
C4H8 *
 dichloromethane

N  Param.: 1.11

sN Param.: 0.98		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-methyl-4-vinyl-benzene
C9H10 *
 dichloromethane

N  Param.: 1.70

sN Param.: 1.06		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methyl-buta-1,3-diene (isoprene)
C5H8 *
 dichloromethane

N  Param.: 1.10

sN Param.: 0.98		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2,3,3-trimethyl-but-1-ene
C7H14 *
 dichloromethane

N  Param.: 0.06

sN Param.: 1.07		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3-dimethyl-but-1-ene
C6H12 *
 dichloromethane

N  Param.: 0.65

sN Param.: 1.00		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,4,4-trimethyl-pent-1-ene
C8H16 *
 dichloromethane

N  Param.: 0.79

sN Param.: 1.07		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-methyl-but-1-ene
C5H10 *
 dichloromethane

N  Param.: 1.00

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,4-dimethyl-penta-1,4-diene
C7H12 *
 dichloromethane

N  Param.: 0.54

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,5-dimethyl-hexa-1,5-diene
C8H14 *
 dichloromethane

N  Param.: 1.14

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,6-dimethyl-hepta-1,6-diene
C9H16 *
 dichloromethane

N  Param.: 1.69

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,7-dimethylocta-1,7-diene
C10H18 *
 dichloromethane

N  Param.: 1.58

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
buta-1,3-diene
C4H6 *
 dichloromethane

N  Param.: -0.87

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(Z)-penta-1,3-diene
C5H8 *
 dichloromethane

N  Param.: 0.66

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(E,E)-hexa-2,4-diene
C6H10 *
 dichloromethane

N  Param.: 1.17

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,3-dimethyl-buta-1,3-diene
C6H10 *
 dichloromethane

N  Param.: 1.17

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(E)-penta-1,3-diene
C5H8 *
 dichloromethane

N  Param.: 1.49

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
4-methyl-penta-1,3-diene
C6H10 *
 dichloromethane

N  Param.: 2.60

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(E)-2-methyl-penta-1,3-diene
C6H10 *
 dichloromethane

N  Param.: 3.09

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclohexa-1,3-diene
C6H8 *
 dichloromethane

N  Param.: 0.67

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclohepta-1,3-diene
C7H10 *
 dichloromethane

N  Param.: 0.06

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cycloocta-1,3-diene
C8H12 *
 dichloromethane

N  Param.: -0.50

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclopentadiene
C5H6 *
 dichloromethane

N  Param.: 2.30

sN Param.: 1.06		 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
tetramethylethylene
C6H12 *
 dichloromethane

N  Param.: -1.00

sN Param.: 1.40		 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2-methylallyl)benzene
C10H12 *
 dichloromethane

N  Param.: 0.25

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
alpha-methylstyrene
C9H10 *
 dichloromethane

N  Param.: 2.35

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-cyclopropylpropene
C6H10 *
 dichloromethane

N  Param.: 2.60

sN Param.: 1.00		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(Z)-phenylpropene
C9H10 *
 dichloromethane

N  Param.: -1.07

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclopentene
C5H8 *
 dichloromethane

N  Param.: -1.55

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
norbornene
C7H10 *
 dichloromethane

N  Param.: -0.25

sN Param.: 1.09		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(1S)-(-)-alpha-pinene
C10H16 *
 dichloromethane

N  Param.: 0.68

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1-methylcyclopentene
C6H10 *
 dichloromethane

N  Param.: 1.18

sN Param.: 1.17		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(E)-but-2-ene
C4H8 *
 dichloromethane

N  Param.: -2.45

sN Param.: 1.10		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,4,6-trimethylstyrene
C11H14 *
 dichloromethane

N  Param.: 0.68

sN Param.: 1.09		 *** Macromolecules 2005, 38, 33-40
10.1021/ma048389o
6,6-dimethylfulvene
C8H10 *
 MeCN

N  Param.: 3.93

sN Param.: 0.88		 *** Eur. J. Org. Chem. 2009, , 1202-1206
10.1002/ejoc.200801099
6-(4-dimethylamino-phenyl)fulvene
C14H15N *
 MeCN

N  Param.: 6.72

sN Param.: 0.87		 *** Eur. J. Org. Chem. 2009, , 1202-1206
10.1002/ejoc.200801099
6-(julolidin-9-yl)fulvene
C18H19N *
 MeCN

N  Param.: 7.79

sN Param.: 1.06		 *** Eur. J. Org. Chem. 2009, , 1202-1206
10.1002/ejoc.200801099
2-methyl-pent-1-ene
*
 dichloromethane

N  Param.: 0.84

sN Param.: 1.06		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b