Cationic Metal-π-Complexes
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
fc(Ph)CH+   |
E Param.: -2.64 |
 |
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
fc(ani)CH+  |
E Param.: -2.90, Deviation: ±0.09 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc(Me)CH+  |
E Param.: -2.57 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc2CH+  |
E Param.: -8.54, Deviation: ±0.53 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H7+-Fe(CO)3  |
E Param.: -3.49, Deviation: ±0.17 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H9+-Fe(CO)3  |
E Param.: -9.21, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H7+-Fe(CO)3  |
E Param.: -7.76, Deviation: ±0.31 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H6OMe+-Fe(CO)3  |
E Param.: -8.94, Deviation: ±0.13 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
propyn-1-ylium-Co2(CO)6  |
E Param.: -0.84, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-proyn-ylium-Co2(CO)6  |
E Param.: -0.97, Deviation: ±0.08 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-phenylpropyn-1-ylium-Co2(CO)6  |
E Param.: -1.58, Deviation: ±0.58 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6  |
E Param.: -1.60, Deviation: ±0.34 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)  |
E Param.: -6.19, Deviation: ±0.44 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
Pd-allyl cation  |
E Param.: -10.11, Deviation: ±0.96 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,3-diphenylpropyn-1-ylium-Cr(CO)3  |
E Param.: 1.07, Deviation: ±0.30 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3  |
E Param.: -0.25, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
dicarbonyl(cyclopentadienyl)propene-iron(II)  |
E Param.: -11.20 |
|
Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)  |
E Param.: -14.14 |
|
Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)  |
E Param.: -14.21 |
|
Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)  |
E Param.: -14.46 |
|
Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |