Acceptor-Substituted Ethylenes
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| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
3-methylcyclopentenone  |
DMSO | E Param.: -28.90 |  | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
2-methylcyclopentenone |
DMSO | E Param.: -22.10 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclopentenone |
DMSO | E Param.: -20.60 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
furan-2(5H)-one |
DMSO | E Param.: -20.70 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
2-methylcyclohexenone |
DMSO | E Param.: -27.50 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclohexenone |
DMSO | E Param.: -22.10 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
dihydro-2H-pyran-2-one |
DMSO | E Param.: -21.80 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylenetetrahydropyran-2-one |
DMSO | E Param.: -19.50 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylenedihydrofuranone |
DMSO | E Param.: -19.40 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylcyclohexenone |
DMSO | E Param.: -29.60 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cycloheptenone |
DMSO | E Param.: -22.00 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -17.00 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.84 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.25 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -17.42 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -11.68 | | Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295 |
4-phenylbut-3-yn-2-one |
E Param.: -16.90 |  | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
hex-3-yn-2-one |
E Param.: -17.90 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
butynone |
E Param.: -16.60 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium |
DMSO | E Param.: -10.09 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.80 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.48 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.79 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -12.02 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
(E)-1,3-diphenylprop-2-en-1-one (in DMSO) |
DMSO | E Param.: -19.39 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
(E)-4-phenylbut-3-en-2-one (in DMSO) |
DMSO | E Param.: -23.01 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
cinnamonitrile (in DMSO) |
DMSO | E Param.: -24.60 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
methyl prop-2-enoate (in DMSO) |
DMSO | E Param.: -18.84 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl prop-2-enoate (in DMSO) |
DMSO | E Param.: -19.07 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
tert-butyl prop-2-enoate (in DMSO) |
DMSO | E Param.: -20.22 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
N,N-dimethylprop-2-enamide (in DMSO) |
DMSO | E Param.: -23.54 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethenylsulfonylbenzene (in DMSO) |
DMSO | E Param.: -18.36 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
acrylonitrile (in DMSO) |
DMSO | E Param.: -19.05 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
but-3-en-2-one (in DMSO) |
DMSO | E Param.: -16.76 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
1-phenylprop-2-en-1-one (in DMSO) |
DMSO | E Param.: -15.25 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl 2-methylprop-2-enoate (in DMSO) |
DMSO | E Param.: -22.77 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl (E)-but-2-enoate (in DMSO) |
DMSO | E Param.: -23.59 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl cinnamate (in DMSO) |
DMSO | E Param.: -24.52 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO) |
DMSO | E Param.: -24.69 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethenesulfonyl fluoride (ESF) |
DMSO | E Param.: -12.09 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
2-phenylethene-1-sulfonyl fluoride |
DMSO | E Param.: -16.63 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
maleic anhydride |
DMSO | E Param.: -11.31 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
N-methyl maleimide |
DMSO | E Param.: -14.07 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
fumaronitrile |
DMSO | E Param.: -15.71 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
diethyl fumarate |
DMSO | E Param.: -17.79 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
diethyl maleate |
DMSO | E Param.: -19.49 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
(ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -7.50 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
(2-phenylethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -12.93 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -13.88 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline |
DMSO | E Param.: -16.53 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |