Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
Te-BTM (in CH2Cl2)
C15H12N2Te*
dichloromethane

N  Param.: 14.62

sN Param.: 0.66
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
Se-DHPB (in CH2Cl2)
C10H10N2Se*
dichloromethane

N  Param.: 15.16

sN Param.: 0.66
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
Se-tetramisole (Se-TM) (in CH2Cl2)
C11H12N2Se*
dichloromethane

N  Param.: 15.26

sN Param.: 0.60
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
Se-BTM (in CH2Cl2)
C15H12N2Se*
dichloromethane

N  Param.: 14.27

sN Param.: 0.63
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
Se-HBTM (in CH2Cl2)
C16H14N2Se*
dichloromethane

N  Param.: 14.42

sN Param.: 0.67
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
Se-HyperBTM (in DCM)
C19H20N2Se*
dichloromethane

N  Param.: 16.11

sN Param.: 0.58
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
Te-DHPB (in CH2Cl2)
C10H10N2Te*
dichloromethane

N  Param.: 16.63

sN Param.: 0.65
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
tetramisole (TM) (in CH2Cl2)
C11H12N2S*
dichloromethane

N  Param.: 13.86

sN Param.: 0.68
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
BTM (in CH2Cl2)
C15H12N2S*
dichloromethane

N  Param.: 13.06

sN Param.: 0.73
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
7-F-BTM (in CH2Cl2)
C15H11FN2S*
dichloromethane

N  Param.: 13.46

sN Param.: 0.66
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
7-MeO-BTM (in CH2Cl29
C16H14N2OS*
dichloromethane

N  Param.: 13.15

sN Param.: 0.75
***Angew. Chem. Int. Ed. 2025, EarlyView, e202514865
10.1002/anie.202514865
benzoate (in 90AN10W)
*
aq MeCN

N  Param.: 11.30

sN Param.: 0.72
**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 90A10W)
*
aq acetone

N  Param.: 12.71

sN Param.: 0.68
***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 80A20W)
*
aq acetone

N  Param.: 12.50

sN Param.: 0.60
**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
p-nitrobenzoate (in acetone)
*
acetone

N  Param.: 18.74

sN Param.: 0.68
***J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
3,5-dinitrobenzoate (in acetone)
*
acetone

N  Param.: 18.80

sN Param.: 0.62
**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
tetraethylstannane (in 1,2-DCE)
*
1,2-dichloroethane

N  Param.: -1.90

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrapropylstannane (in 1,2-DCE)
*
1,2-dichloroethane

N  Param.: -0.50

sN Param.: 1.13
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetra-sec.butylstannane (in 1,2-DCE)
*
1,2-dichloroethane

N  Param.: -1.10

sN Param.: 1.15
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-chlorophenethyl)trimethylstannane
*
1,2-dichloroethane

N  Param.: -1.80

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(phenethyl)stannane
*
1,2-dichloroethane

N  Param.: -1.10

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(2-([1,1'-biphenyl]-4-yl)ethyl)trimethylstannane
*
1,2-dichloroethane

N  Param.: -0.80

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(4-methylphenethyl)stannane
*
1,2-dichloroethane

N  Param.: -0.50

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-(tert-butyl)phenethyl)trimethylstannane
*
1,2-dichloroethane

N  Param.: -0.30

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-methoxyphenethyl)trimethylstannane
*
1,2-dichloroethane

N  Param.: 0.20

sN Param.: 1.10
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839