Mayr's Database of Reactivity Parameters

Nucleophiles

3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 Found 1292 molecules, displaying page 7 of 13 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium-2-ide (in THF)
C21H26N2*
 THF

N  Param.: 23.35

sN Param.: 0.40		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
1,3,4-triphenyl-1H-1,2,4-triazol-4-ium-5-ide (in THF)
C20H15N3*
 THF

N  Param.: 14.07

sN Param.: 0.84		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
thioacetate (in MeCN)
*
 MeCN

N  Param.: 21.20

sN Param.: 0.63		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
O-ethyl dithiocarbonate (in MeCN)
*
 MeCN

N  Param.: 19.30

sN Param.: 0.69		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
O-isopropyl dithiocarbonate (in MeCN)
*
 MeCN

N  Param.: 18.27

sN Param.: 0.78		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
N,N-dimethyl dithiocarbamate (in MeCN)
*
 MeCN

N  Param.: 20.93

sN Param.: 0.69		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
pyrrolidin-1-yl dithiocarbamate (in MeCN)
*
 MeCN

N  Param.: 22.40

sN Param.: 0.63		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
piperidin-1-yl dithiocarbamate (in MeCN)
*
 MeCN

N  Param.: 23.84

sN Param.: 0.57		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
4-methylpiperazin-1-yl dithiocarbamate (in MeCN)
*
 MeCN

N  Param.: 23.61

sN Param.: 0.57		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
morpholin-1-yl dithiocarbamate (in MeCN)
*
 MeCN

N  Param.: 21.72

sN Param.: 0.64		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
triphenylphosphine (in THF)
*
 THF

N  Param.: 13.59

sN Param.: 0.66		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
4-(dimethylamino)pyridine (in THF)
*
 THF

N  Param.: 15.90

sN Param.: 0.66		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
DBU (in THF)
*
 THF

N  Param.: 16.12

sN Param.: 0.67		***Angew. Chem. Int. Ed. 2011, 50, 6915-6919
10.1002/anie.201102435
toluene
C7H8*
 dichloromethane

N  Param.: -4.36

sN Param.: 1.77		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(E)-propenylbenzene
C9H10*
 dichloromethane

N  Param.: -0.49

sN Param.: 1.18		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-methylthiophene
C5H6S*
 dichloromethane

N  Param.: 1.35

sN Param.: 0.99		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
allyltrimethylsilane
C6H14Si*
 dichloromethane

N  Param.: 1.68

sN Param.: 1.00		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
triethylsilane
C6H16Si*
 dichloromethane

N  Param.: 3.58

sN Param.: 0.70		***J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
methylenecyclohexane
C7H12*
 dichloromethane

N  Param.: 1.16

sN Param.: 1.04		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-chloropropene
C3H5Cl*
 dichloromethane

N  Param.: -3.65

sN Param.: 1.97		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1-hexene
C6H12*
 dichloromethane

N  Param.: -2.77

sN Param.: 1.41		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
allylchlorodimethylsilane
C5H11ClSi*
 dichloromethane

N  Param.: -0.57

sN Param.: 1.06		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3,3-trimethyl-but-1-ene
C7H14*
 dichloromethane

N  Param.: 0.06

sN Param.: 1.07		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3-dimethyl-but-1-ene
C6H12*
 dichloromethane

N  Param.: 0.65

sN Param.: 1.00		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,4,4-trimethyl-pent-1-ene
C8H16*
 dichloromethane

N  Param.: 0.79

sN Param.: 1.07		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
furan
C4H4O*
 dichloromethane

N  Param.: 1.33

sN Param.: 1.29		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
norbornene
C7H10*
 dichloromethane

N  Param.: -0.25

sN Param.: 1.09		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1-methylcyclopentene
C6H10*
 dichloromethane

N  Param.: 1.18

sN Param.: 1.17		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
trifluoroethanol
C2H3F3O*
 TFE

N  Param.: 1.11

sN Param.: 0.96		***J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
4-(dimethylamino)pyridine (in MeCN)
C7H10N2*
 MeCN

N  Param.: 15.51

sN Param.: 0.62		***J. Phys. Chem. A 2012, 116, 8494-8499
10.1021/jp3049247
2-methyl-pent-1-ene
*
 dichloromethane

N  Param.: 0.84

sN Param.: 1.06		*****J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
hydrazine (in MeCN)
*
 MeCN

N  Param.: 16.45

sN Param.: 0.56		***Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
1,1-dimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 11.72

sN Param.: 0.73		***Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
trimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 12.43

sN Param.: 0.75		***Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
1,1-dimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 22.41

sN Param.: 0.45		***Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
trimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 17.75

sN Param.: 0.53		***Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
(5-methyl-furan-2-yl) pinacol boronate
*
 MeCN

N  Param.: 2.90

sN Param.: 0.98		***Chem. Sci. 2012, 3, 878-882
10.1039/c2sc00883a
(5-methyl-furan-2-yl) MDA boronate
*
 MeCN

N  Param.: 6.38

sN Param.: 0.86		***Chem. Sci. 2012, 3, 878-882
10.1039/c2sc00883a
(5-methyl-furan-2-yl) MIDA boronate
*
 MeCN

N  Param.: 1.84

sN Param.: 1.26		**Chem. Sci. 2012, 3, 878-882
10.1039/c2sc00883a
(5-methyl-furan-2-yl) trifluoroborate
*
 MeCN

N  Param.: 7.66

sN Param.: 1.04		***Chem. Sci. 2012, 3, 878-882
10.1039/c2sc00883a
tetrakis(5-methyl-furan-2-yl)borate
*
 MeCN

N  Param.: 9.09

sN Param.: 1.12		***Chem. Sci. 2012, 3, 878-882
10.1039/c2sc00883a
(5-methyl-furan-2-yl)(1,1,1-tris(methoxy)ethane)borate
*
 MeCN

N  Param.: 12.55

sN Param.: 0.92		***Chem. Sci. 2012, 3, 878-882
10.1039/c2sc00883a
dipp Imd boronate
*
 dichloromethane

N  Param.: 9.55

sN Param.: 0.81		***Org. Lett. 2012, 14, 82-85
10.1021/ol202836p
Me2 Imd boronate
*
 dichloromethane

N  Param.: 11.88

sN Param.: 0.71		***Org. Lett. 2012, 14, 82-85
10.1021/ol202836p
imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.09

sN Param.: 0.51		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.03

sN Param.: 0.50		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.29

sN Param.: 0.51		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2,4-dimethyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 20.69

sN Param.: 0.60		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-nitro-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 14.81

sN Param.: 0.71		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-formyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 16.06

sN Param.: 0.68		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-formyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 16.40

sN Param.: 0.67		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
benzimidazole anion (in DMSO)
*
 DMSO

N  Param.: 19.13

sN Param.: 0.55		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
benzotriazole anion (in DMSO)
*
 DMSO

N  Param.: 16.29

sN Param.: 0.65		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
purine anion (in DMSO)
*
 DMSO

N  Param.: 15.03

sN Param.: 0.77		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
theophylline anion (in DMSO)
*
 DMSO

N  Param.: 14.78

sN Param.: 0.71		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
adenine anion (in DMSO)
*
 DMSO

N  Param.: 18.00

sN Param.: 0.55		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
uracil anion (in DMSO)
*
 DMSO

N  Param.: 17.04

sN Param.: 0.63		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
thymine anion (in DMSO)
*
 DMSO

N  Param.: 17.63

sN Param.: 0.62		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
1-methyl uracil anion (in DMSO)
*
 DMSO

N  Param.: 16.36

sN Param.: 0.69		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-nitro-imidazole anion (in water)
*
 water

N  Param.: 11.37

sN Param.: 0.53		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-formyl-imidazole anion (in water)
*
 water

N  Param.: 11.07

sN Param.: 0.50		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
benzotriazole anion (in water)
*
 water

N  Param.: 11.52

sN Param.: 0.67		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
purine anion (in water)
*
 water

N  Param.: 11.00

sN Param.: 0.54		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
theophylline anion (in water)
*
 water

N  Param.: 10.06

sN Param.: 0.71		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
adenine anion (in water)
*
 water

N  Param.: 10.93

sN Param.: 0.62		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
guanine anion (in water)
*
 water

N  Param.: 11.63

sN Param.: 0.59		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
9-methyl guanine anion (in water)
*
 water

N  Param.: 10.77

sN Param.: 0.65		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
guanosine anion (in water)
*
 water

N  Param.: 12.09

sN Param.: 0.52		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
uracil anion (in water)
*
 water

N  Param.: 10.75

sN Param.: 0.53		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
thymine anion (in water)
*
 water

N  Param.: 11.17

sN Param.: 0.51		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
1-methyl uracil anion (in water)
*
 water

N  Param.: 8.54

sN Param.: 0.77		***Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
N-(1-phenylvinyl)acetamide
C10H11NO*
 MeCN

N  Param.: 5.73

sN Param.: 0.97		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(1-(p-tolyl)vinyl)acetamide
C11H13NO*
 MeCN

N  Param.: 6.57

sN Param.: 0.91		**Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(1-(4-methoxyphenyl)vinyl)acetamide
C11H13NO2*
 MeCN

N  Param.: 7.06

sN Param.: 0.85		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(1-(4-chlorophenyl)vinyl)acetamide
C10H10ClNO*
 MeCN

N  Param.: 5.60

sN Param.: 1.00		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
benzyl (1-phenylvinyl)carbamate
C16H15NO2*
 MeCN

N  Param.: 6.21

sN Param.: 0.87		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(1-phenylvinyl)benzamide
C15H13NO*
 MeCN

N  Param.: 5.44

sN Param.: 1.00		*Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(1-(naphthalen-2-yl)vinyl)acetamide
C14H13NO*
 MeCN

N  Param.: 6.28

sN Param.: 0.95		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(3,4-dihydronaphthalen-1-yl)acetamide
C12H13NO*
 MeCN

N  Param.: 4.91

sN Param.: 0.87		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(cyclohex-1-en-1-yl)acetamide
C8H13NO*
 MeCN

N  Param.: 5.64

sN Param.: 0.79		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(cyclopent-1-en-1-yl)acetamide
C7H11NO*
 MeCN

N  Param.: 7.06

sN Param.: 0.87		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
N-(3,3-dimethylbut-1-en-2-yl)acetamide
C8H15NO*
 MeCN

N  Param.: 4.61

sN Param.: 0.98		***Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
fluoride (in MeOH)
F*
 MeOH

N  Param.: 11.31

sN Param.: 0.63		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 80% aq EtOH)
F*
 water-EtOH mix

N  Param.: 13.20

sN Param.: 0.53		*J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in water)
F*
 water

N  Param.: 7.70

sN Param.: 0.66		*J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 10 % aq MeCN)
F*
 water-MeCN mix

N  Param.: 8.05

sN Param.: 0.64		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 60% aq MeCN)
F*
 water-MeCN mix

N  Param.: 9.75

sN Param.: 0.63		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 80% aq MeCN)
F*
 water-MeCN mix

N  Param.: 11.40

sN Param.: 0.59		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 90% aq MeCN)
F*
 water-MeCN mix

N  Param.: 12.27

sN Param.: 0.59		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 98% aq MeCN)
F*
 water-MeCN mix

N  Param.: 10.88

sN Param.: 0.83		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
1,1,3,3-tetramethylguanidine
C5H13N3*
 dichloromethane

N  Param.: 13.58

sN Param.: 0.77		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
2-benzyl-1,1,3,3-tetramethylguanidine
C12H19N3*
 dichloromethane

N  Param.: 14.36

sN Param.: 0.79		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
1,3-dimethylimidazolidin-2-imine
C5H11N3*
 dichloromethane

N  Param.: 12.46

sN Param.: 0.87		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
N-(1,3-dimethylimidazolidin-2-ylidene)-1-phenylmethanamine
C12H17N3*
 dichloromethane

N  Param.: 14.00

sN Param.: 0.70		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
2,3,5,6-tetrahydro-1H-imidazo[1,2-a]imidazole (TBO)
C5H9N3*
 dichloromethane

N  Param.: 14.44

sN Param.: 0.79		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyrimidine (TBN)
C6H11N3*
 dichloromethane

N  Param.: 16.15

sN Param.: 0.73		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
1-methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine (MeTBD)
C8H15N3*
 dichloromethane

N  Param.: 14.43

sN Param.: 0.81		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine
C7H13N3*
 dichloromethane

N  Param.: 16.16

sN Param.: 0.75		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
DBN (in CH2Cl2)
*
 dichloromethane

N  Param.: 15.50

sN Param.: 0.76		***ChemCatChem 2012, 4, 993-999
10.1002/cctc.201200143
(S,E)-2-(diphenyl(trimethylsiloxy)methyl)-1-styrylpyrrolidine
C28H33NOSi*
 MeCN

N  Param.: 10.56

sN Param.: 1.01		***Angew. Chem. Int. Ed. 2012, 51, 5739-5742
10.1002/anie.201201240